@article{6e8efbf99f4b43cfa9c0a8f12faf75db,
title = "Structure and bonding in IrO2Ph2PCH 2·CH2·PPh22PF 6 and in IrBrCOPPh32C2CN4",
author = "McGinnety, {J. A.} and Ibers, {James A.}",
note = "Funding Information: The geometry depicted in Figure 2 differs both from those of the 0, complexes and that of the SO, complex.13 This again indicates that the energy differences among the various possible five- co-ordinate geometries are very small indeed. lye thank Profs. IV. H. Baddley, R. G. Pearson, and D. F. Shriver for helpful discussions. This work was supported by the U.S. National Institutes of Health. (Received, January 9th, 1968; Corn. 033.) This occurs in [Ir(02) (diphos),] &. L. Vaska, Scieme, 1063, 140, 809. J. A. McGinnety, R. J. Doedens, and J . A. Ibers, Science, 1967, 155, 709; Inorg. Chem., 1967, 6, 2243. J . A. Ibers and S. J. La Placa, Science, 1964,145, 920; S. J. La Placa and J. A. Ibers, J . Amer. Chem. Soc., 1966, G. W. Parshall and F. N. Jones, J . Amer. Chem. SOC., 1965, 87, 5356. W. H. Baddley, J . Amer. Chem. Soc., 1966, 88, 4545. P. W. R. Corfield, R. J. Doedens, and J. A. Ibers, Inorg. Chem., 1967,6, 197. L. Vaska and D. L. Catone, J . Amer. Chem. SOC., 1966,88, 5324. D. A. Bekoe and I<. N. Trueblood, private communication. l o M. J. S. Dewar and H. N. Schmeising, Tetrahedron, 1959, 5, 166. l 1 R. S. Rlulliken, Tetrahedron, 1959, 6 , 68. I2B. R. Penfold and W. N. Lipscomb, Acta Cryst., 1961, 14, 589. l 3 S. J . La Placa and J. A. Ibers, Inovg. Chem., 1966,5, 405. 87, 2581. {\textquoteright} A. Sacco, M. Rossi, and C. F. Nobile, Chem. Comm., 1966, 589.",
year = "1968",
doi = "10.1039/C19680000235",
language = "English (US)",
pages = "235--237",
journal = "Chemical Communications (London)",
issn = "0009-241X",
number = "5",
}