Structure and ion transport in polymer-salt complexes

D. F. Shriver; B. L. Papke; M. A. Ratner; R. Dupon; T. Wong; M. Brodwin

doi:10.1016/0167-2738(81)90199-5

Structure and ion transport in polymer-salt complexes

D. F. Shriver^*, B. L. Papke, M. A. Ratner, R. Dupon, T. Wong, M. Brodwin

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

168 Scopus citations

Abstract

Polymer electrolytes based on alkali metal complexes of polyethers and cross-linked polyethers have significant cation mobility, which appears to arise from large-amplitude motions of the polymer. High chain flexibility not only promotes ion transport but it also is important for the initial formation of polymer-salt complexes. Several new polymer electrolyte systems are discussed which contain flexible polymer backbones and high concentrations of polar groups.

Original language	English (US)
Pages (from-to)	83-88
Number of pages	6
Journal	Solid State Ionics
Volume	5
Issue number	C
DOIs	https://doi.org/10.1016/0167-2738(81)90199-5
State	Published - Oct 1981

Funding

We appreciate many informative discussions with D.H. Whitmore and the ready exchange of information with P.V. Wright and M. Armand. Our research in polymer electrolytes was supported by the Office of Naval Research, and by the NSF MFL program through grant DMR-79-23573 to the Northwestern University Materials Research Center.

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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abstract = "Polymer electrolytes based on alkali metal complexes of polyethers and cross-linked polyethers have significant cation mobility, which appears to arise from large-amplitude motions of the polymer. High chain flexibility not only promotes ion transport but it also is important for the initial formation of polymer-salt complexes. Several new polymer electrolyte systems are discussed which contain flexible polymer backbones and high concentrations of polar groups.",

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AU - Shriver, D. F.

AU - Papke, B. L.

AU - Ratner, M. A.

AU - Dupon, R.

AU - Wong, T.

AU - Brodwin, M.

N1 - Funding Information: We appreciate many informative discussions with D.H. Whitmore and the ready exchange of information with P.V. Wright and M. Armand. Our research in polymer electrolytes was supported by the Office of Naval Research, and by the NSF MFL program through grant DMR-79-23573 to the Northwestern University Materials Research Center.

PY - 1981/10

Y1 - 1981/10

N2 - Polymer electrolytes based on alkali metal complexes of polyethers and cross-linked polyethers have significant cation mobility, which appears to arise from large-amplitude motions of the polymer. High chain flexibility not only promotes ion transport but it also is important for the initial formation of polymer-salt complexes. Several new polymer electrolyte systems are discussed which contain flexible polymer backbones and high concentrations of polar groups.

AB - Polymer electrolytes based on alkali metal complexes of polyethers and cross-linked polyethers have significant cation mobility, which appears to arise from large-amplitude motions of the polymer. High chain flexibility not only promotes ion transport but it also is important for the initial formation of polymer-salt complexes. Several new polymer electrolyte systems are discussed which contain flexible polymer backbones and high concentrations of polar groups.

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Structure and ion transport in polymer-salt complexes

Abstract

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