Structure formation and properties of composite conductive fibers with doped phthalocyanines and a rigid rod matrix

Konstantinos Beltsios; Stephen H. Carr

Structure formation and properties of composite conductive fibers with doped phthalocyanines and a rigid rod matrix

Konstantinos Beltsios^*, Stephen H. Carr

^*Corresponding author for this work

Materials Science and Engineering

Research output: Contribution to journal › Conference article › peer-review

2 Scopus citations

Abstract

Phthalocyanine (Pc) compounds, such as NiPc or (SiPcO)_n, are incorporated in fibers having as matrix a rigid rod polymer, such as poly(p-phenyleneterephthalamide) (PPTA) or poly(p-phenylene benzobisthiazole) (PBT). The structure and properties of the composite fibers are discussed in terms of a phase formation model advanced for the structure formation of neat rigid rod fibers. Optical microscopy of metallographically prepared longitudinal and transverse sections of fibers embedded in resin showed strong contrast in the color of the two components (light colored rigid rod polymers and purple, blue or reddish phthalocyanine compounds). The analysis presented provides a reference basis for a TEM study of our fibers, but it may serve, as well, as a guide for other composite fibers with a rigid rod matrix.

Original language	English (US)
Pages (from-to)	163-164
Number of pages	2
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	30
Issue number	1
State	Published - Apr 1 1989
Event	Papers Presented at the Dallas, Texas Meeting - Dallas, TX, USA Duration: Apr 9 1989 → Apr 14 1989

ASJC Scopus subject areas

Polymers and Plastics
Materials Science(all)

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title = "Structure formation and properties of composite conductive fibers with doped phthalocyanines and a rigid rod matrix",

abstract = "Phthalocyanine (Pc) compounds, such as NiPc or (SiPcO)n, are incorporated in fibers having as matrix a rigid rod polymer, such as poly(p-phenyleneterephthalamide) (PPTA) or poly(p-phenylene benzobisthiazole) (PBT). The structure and properties of the composite fibers are discussed in terms of a phase formation model advanced for the structure formation of neat rigid rod fibers. Optical microscopy of metallographically prepared longitudinal and transverse sections of fibers embedded in resin showed strong contrast in the color of the two components (light colored rigid rod polymers and purple, blue or reddish phthalocyanine compounds). The analysis presented provides a reference basis for a TEM study of our fibers, but it may serve, as well, as a guide for other composite fibers with a rigid rod matrix.",

author = "Konstantinos Beltsios and Carr, {Stephen H.}",

year = "1989",

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language = "English (US)",

volume = "30",

pages = "163--164",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

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note = "Papers Presented at the Dallas, Texas Meeting ; Conference date: 09-04-1989 Through 14-04-1989",

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TY - JOUR

T1 - Structure formation and properties of composite conductive fibers with doped phthalocyanines and a rigid rod matrix

AU - Beltsios, Konstantinos

AU - Carr, Stephen H.

PY - 1989/4/1

Y1 - 1989/4/1

N2 - Phthalocyanine (Pc) compounds, such as NiPc or (SiPcO)n, are incorporated in fibers having as matrix a rigid rod polymer, such as poly(p-phenyleneterephthalamide) (PPTA) or poly(p-phenylene benzobisthiazole) (PBT). The structure and properties of the composite fibers are discussed in terms of a phase formation model advanced for the structure formation of neat rigid rod fibers. Optical microscopy of metallographically prepared longitudinal and transverse sections of fibers embedded in resin showed strong contrast in the color of the two components (light colored rigid rod polymers and purple, blue or reddish phthalocyanine compounds). The analysis presented provides a reference basis for a TEM study of our fibers, but it may serve, as well, as a guide for other composite fibers with a rigid rod matrix.

AB - Phthalocyanine (Pc) compounds, such as NiPc or (SiPcO)n, are incorporated in fibers having as matrix a rigid rod polymer, such as poly(p-phenyleneterephthalamide) (PPTA) or poly(p-phenylene benzobisthiazole) (PBT). The structure and properties of the composite fibers are discussed in terms of a phase formation model advanced for the structure formation of neat rigid rod fibers. Optical microscopy of metallographically prepared longitudinal and transverse sections of fibers embedded in resin showed strong contrast in the color of the two components (light colored rigid rod polymers and purple, blue or reddish phthalocyanine compounds). The analysis presented provides a reference basis for a TEM study of our fibers, but it may serve, as well, as a guide for other composite fibers with a rigid rod matrix.

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M3 - Conference article

AN - SCOPUS:0024495914

VL - 30

SP - 163

EP - 164

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

SN - 0032-3934

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T2 - Papers Presented at the Dallas, Texas Meeting

Y2 - 9 April 1989 through 14 April 1989

ER -