Structure of Nitrosyltris(triphenylphosphine)rhodium, Rh(NO)(P(C6H5)3)3

James A. Kaduk*, James A. Ibers

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

The structure of nitrosyltris(triphenylphosphine)rhodium, Rh(NO)‐(P(C6H5)3)3, has been determined from three‐dimensional X‐ray data. The compound crystallizes in the space group P3 of the trigonal system with three molecules in a unit cell of dimensions a = 19.057(4) and c = 10.799(2)Å. Least‐squares refinement of the 162 variables has led to a value of the conventional R index (on F) of 0.052 for the 5456 independent reflections having F2o > 3 σ (F2o). There are three independent molecules in the unit cell, one‐third of each being unique. The best first approximation is to describe the complex as a tetrahedral Rh( ‐I) complex; average parameters: Rh—P = 2.350(3), Rh—N = 1.759(13), N—O = 1.27(2) Å, P—Rh—P = 102.2(6), N—Rh—P = 116.0(5), Rh—N—O = 156.7(26)°. The nitrosyl groups are disordered about the threefold axes. The structure is compared with other metal nitrosyl phosphine complexes and the metal‐nitrosyl bonding is discussed.

Original languageEnglish (US)
Pages (from-to)143-148
Number of pages6
JournalIsrael Journal of Chemistry
Volume15
Issue number3-4
DOIs
StatePublished - 1976

ASJC Scopus subject areas

  • Chemistry(all)

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