Structure of potassium hydroxide: An x-ray and infrared study

James A. Ibers*, Junji Kumamoto, Robert G. Snyder

*Corresponding author for this work

Research output: Contribution to journalArticle

26 Scopus citations

Abstract

Infrared evidence has been obtained which indicates that the crystal structure of KOH reported in the literature is incorrect. A subsequent x-ray examination has shown that this is the case and has led to a structure compatible with the infrared spectrum. KOH crystallizes in the monoclinic space group C22-P21 (chosen over P21/m on the basis of the infrared evidence), with two molecules in a cell of dimensions a= 3.95, b=4.00, c=5.73 A, β=103.6°. Each potassium atom is surrounded by a distorted octahedron of oxygen atoms. There is an oxygen-oxygen zigzag chain parallel to the b axis. Stereochemical arguments are advanced to suggest that the hydrogen atoms are near to or lie in the plane of the zigzag oxygen chain; infrared data obtained at -180°C for KOH and KOD are interpreted as supporting the placement of the hydrogen atoms in ordered positions along the chain with the O-H⋯-O bonds (of length 3.35 A) nearly or exactly linear. It is argued that breaking of these hydrogen bonds will lead to the high-temperature cubic structure of KOH reported in the literature.

Original languageEnglish (US)
Pages (from-to)1164-1170
Number of pages7
JournalThe Journal of Chemical Physics
Volume33
Issue number4
DOIs
StatePublished - Jan 1 1960

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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