Structures of the multireceptor vaulted cyclidene complexes

Nathaniel W. Alcock; Daryle H. Busch; Piotr J. Chmielewski; B. K. Coltrain; Thomas J. Meade

doi:10.1016/0020-1693(96)05057-8

Structures of the multireceptor vaulted cyclidene complexes

Nathaniel W. Alcock^*, Daryle H. Busch, Piotr J. Chmielewski, B. K. Coltrain, Thomas J. Meade

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The preparations and structures of three vaulted cyclidene complexes are compared with the two previously reported. All show similar structures with large rigid cavities partly closed off by the piperidine risers, illustrating in particular the attractive effect of van der Waals forces resulting in the incorporation of solvent molecules or [PF₆]^- ions nesting on the edges of the cavities. However, the detailed geometries vary, according to the nature of the ligand substituents, the metal, the counter-ion and the lattice solvent molecules. These give rise to differing orientations of the capping aromatic rings and the piperidine risers.

Original language	English (US)
Pages (from-to)	109-118
Number of pages	10
Journal	Inorganica Chimica Acta
Volume	246
Issue number	1-2 SPEC. ISSUE
DOIs	https://doi.org/10.1016/0020-1693(96)05057-8
State	Published - May 1996

Keywords

Crystal structure
Multireceptor complexes
Vaulted cyclidene complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0020-1693(96)05057-8

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@article{18eb1d08f19641a1a111f75172ce1065,

title = "Structures of the multireceptor vaulted cyclidene complexes",

abstract = "The preparations and structures of three vaulted cyclidene complexes are compared with the two previously reported. All show similar structures with large rigid cavities partly closed off by the piperidine risers, illustrating in particular the attractive effect of van der Waals forces resulting in the incorporation of solvent molecules or [PF6]- ions nesting on the edges of the cavities. However, the detailed geometries vary, according to the nature of the ligand substituents, the metal, the counter-ion and the lattice solvent molecules. These give rise to differing orientations of the capping aromatic rings and the piperidine risers.",

keywords = "Crystal structure, Multireceptor complexes, Vaulted cyclidene complexes",

author = "Alcock, {Nathaniel W.} and Busch, {Daryle H.} and Chmielewski, {Piotr J.} and Coltrain, {B. K.} and Meade, {Thomas J.}",

note = "Funding Information: We thank Rr J. Gallucci and Dr A. Willis for data collection for 1 and 2, respectively, and Dr S. Davis for carrying out preliminary analysis for 1. The financial support of the US National Science Foundation and the US National Institute of Health is gratefully acknowledged. The Warwick-Kansas collaboration has been greatly helped by travel support from NATO.",

year = "1996",

month = may,

doi = "10.1016/0020-1693(96)05057-8",

language = "English (US)",

volume = "246",

pages = "109--118",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "1-2 SPEC. ISSUE",

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TY - JOUR

T1 - Structures of the multireceptor vaulted cyclidene complexes

AU - Alcock, Nathaniel W.

AU - Busch, Daryle H.

AU - Chmielewski, Piotr J.

AU - Coltrain, B. K.

AU - Meade, Thomas J.

N1 - Funding Information: We thank Rr J. Gallucci and Dr A. Willis for data collection for 1 and 2, respectively, and Dr S. Davis for carrying out preliminary analysis for 1. The financial support of the US National Science Foundation and the US National Institute of Health is gratefully acknowledged. The Warwick-Kansas collaboration has been greatly helped by travel support from NATO.

PY - 1996/5

Y1 - 1996/5

N2 - The preparations and structures of three vaulted cyclidene complexes are compared with the two previously reported. All show similar structures with large rigid cavities partly closed off by the piperidine risers, illustrating in particular the attractive effect of van der Waals forces resulting in the incorporation of solvent molecules or [PF6]- ions nesting on the edges of the cavities. However, the detailed geometries vary, according to the nature of the ligand substituents, the metal, the counter-ion and the lattice solvent molecules. These give rise to differing orientations of the capping aromatic rings and the piperidine risers.

AB - The preparations and structures of three vaulted cyclidene complexes are compared with the two previously reported. All show similar structures with large rigid cavities partly closed off by the piperidine risers, illustrating in particular the attractive effect of van der Waals forces resulting in the incorporation of solvent molecules or [PF6]- ions nesting on the edges of the cavities. However, the detailed geometries vary, according to the nature of the ligand substituents, the metal, the counter-ion and the lattice solvent molecules. These give rise to differing orientations of the capping aromatic rings and the piperidine risers.

KW - Crystal structure

KW - Multireceptor complexes

KW - Vaulted cyclidene complexes

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DO - 10.1016/0020-1693(96)05057-8

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VL - 246

SP - 109

EP - 118

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2 SPEC. ISSUE

ER -

Structures of the multireceptor vaulted cyclidene complexes

Abstract

Keywords

ASJC Scopus subject areas

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