Sublattice melting in binary superionic colloidal crystals

Yange Lin*, Monica Olvera De La Cruz

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

In superionic compounds one component premelts, providing high ionic conductivity to solid-state electrolytes. Here we find sublattice melting in colloidal crystals of oppositely charged particles that are highly asymmetric in size and charge in salt solutions. The small particles in ionic compounds melt when the temperature increases, forming a superionic phase. These delocalized small particles in a crystal of large oppositely charged particles, in contrast to superionic phases in atomic systems, form crystals with nonelectroneutral stoichiometric ratios. This generates structures with multiple domains of ionic crystals in percolated superionic phases with adjustable stoichiometries.

Original languageEnglish (US)
Article number032603
JournalPhysical Review E
Volume101
Issue number3
DOIs
StatePublished - Mar 2020

ASJC Scopus subject areas

  • Statistical and Nonlinear Physics
  • Statistics and Probability
  • Condensed Matter Physics

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