77Se and 87Rb Solid State NMR Study of the Structure of Rb2[Pd(Se4)2]·Se8

A. Goldbach; F. Fayon; T. Vosegaard; M. Wachhold; M. G. Kanatzidis; D. Massiot; M. L. Saboungi

doi:10.1021/ic030074m

⁷⁷Se and ⁸⁷Rb Solid State NMR Study of the Structure of Rb₂[Pd(Se₄)₂]·Se₈

A. Goldbach, F. Fayon, T. Vosegaard, M. Wachhold, M. G. Kanatzidis, D. Massiot, M. L. Saboungi^*

^*Corresponding author for this work

Chemistry

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Abstract

The structure of Rb₂[Pd(Se₄)₂]· Se₈ has been investigated using ⁸⁷Rb magic angle spinning and static NMR and ⁷⁷Se magic angle spinning NMR. The number and the integrated intensities of the ⁸⁷Rb and ⁷⁷Se resonances are in full agreement with the crystallographic structure of the compound. The ⁸⁷Rb and ⁷⁷Se nuclear spin interaction parameters have been used to characterize the main structural units of the compound: infinite [Rb(Se₈)]_x^x+ columns and polymeric [Pd(Se ₄)₂]_x^2x- sheet anions.

Original language	English (US)
Pages (from-to)	6996-7000
Number of pages	5
Journal	Inorganic Chemistry
Volume	42
Issue number	22
DOIs	https://doi.org/10.1021/ic030074m
State	Published - Nov 3 2003

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Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "77Se and 87Rb Solid State NMR Study of the Structure of Rb2[Pd(Se4)2]·Se8",

abstract = "The structure of Rb2[Pd(Se4)2]· Se8 has been investigated using 87Rb magic angle spinning and static NMR and 77Se magic angle spinning NMR. The number and the integrated intensities of the 87Rb and 77Se resonances are in full agreement with the crystallographic structure of the compound. The 87Rb and 77Se nuclear spin interaction parameters have been used to characterize the main structural units of the compound: infinite [Rb(Se8)]xx+ columns and polymeric [Pd(Se 4)2]x2x- sheet anions.",

author = "A. Goldbach and F. Fayon and T. Vosegaard and M. Wachhold and Kanatzidis, {M. G.} and D. Massiot and Saboungi, {M. L.}",

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T1 - 77Se and 87Rb Solid State NMR Study of the Structure of Rb2[Pd(Se4)2]·Se8

AU - Goldbach, A.

AU - Fayon, F.

AU - Vosegaard, T.

AU - Wachhold, M.

AU - Kanatzidis, M. G.

AU - Massiot, D.

AU - Saboungi, M. L.

PY - 2003/11/3

Y1 - 2003/11/3

N2 - The structure of Rb2[Pd(Se4)2]· Se8 has been investigated using 87Rb magic angle spinning and static NMR and 77Se magic angle spinning NMR. The number and the integrated intensities of the 87Rb and 77Se resonances are in full agreement with the crystallographic structure of the compound. The 87Rb and 77Se nuclear spin interaction parameters have been used to characterize the main structural units of the compound: infinite [Rb(Se8)]xx+ columns and polymeric [Pd(Se 4)2]x2x- sheet anions.

AB - The structure of Rb2[Pd(Se4)2]· Se8 has been investigated using 87Rb magic angle spinning and static NMR and 77Se magic angle spinning NMR. The number and the integrated intensities of the 87Rb and 77Se resonances are in full agreement with the crystallographic structure of the compound. The 87Rb and 77Se nuclear spin interaction parameters have been used to characterize the main structural units of the compound: infinite [Rb(Se8)]xx+ columns and polymeric [Pd(Se 4)2]x2x- sheet anions.

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SP - 6996

EP - 7000

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

⁷⁷Se and ⁸⁷Rb Solid State NMR Study of the Structure of Rb₂[Pd(Se₄)₂]·Se₈

Abstract

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