Abstract
Atomic layer deposition (ALD) is used to deposit ruthenium-platinum nanostructured catalysts using 2,4-(dimethylpentadienyl)(ethylcyclopentadienyl) ruthenium, trimethyl(methylcyclopentadienyl) platinum, and oxygen as precursors. Transmission electron microscopy shows discrete 1.2 nm nanoparticles decorating the surface of the spherical alumina support. The Ru-Pt particles are crystalline and have a crystal structure similar to pure platinum. X-ray fluorescence measurements show that the nanoparticle composition is controlled by the ratio of metal precursor ALD cycles. X-ray absorption spectroscopy at the Ru K-edge indicates a nearest neighbor Ru-Pt interaction consistent with a bimetallic composition. Methanol decomposition reactions further confirm a Ru-Pt interaction and show enhanced methanol conversion for the bimetallic nanoparticles when compared to catalysts comprised of a mixture of pure Pt and Ru nanoparticles of similar loading. These results demonstrate that ALD is a viable technique for synthesizing mixed-metal nanostructures suitable for catalysis and other applications.
Original language | English (US) |
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Pages (from-to) | 3047-3051 |
Number of pages | 5 |
Journal | Nano letters |
Volume | 10 |
Issue number | 8 |
DOIs | |
State | Published - Aug 11 2010 |
Keywords
- Atomic layer deposition
- bimetallic catalysts
- platinum
- ruthenium
ASJC Scopus subject areas
- Bioengineering
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
- Mechanical Engineering