Supramolecular assembly of hexagonal mesostructured germanium sulfide and selenide nanocomposites incorporating the biologically relevant Fe4S4 cluster

Pantelis N. Trikalitis; Thomas Bakas; Vasilios Papaefthymiou; Mercouri G. Kanatzidis

doi:10.1002/1521-3773(20001215)39:24<4558::AID-ANIE4558>3.0.CO;2-B

Supramolecular assembly of hexagonal mesostructured germanium sulfide and selenide nanocomposites incorporating the biologically relevant Fe₄S₄ cluster

Pantelis N. Trikalitis, Thomas Bakas, Vasilios Papaefthymiou, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Stable hybrid systems are generated by the reaction of adamantane [Ge₄Q₁₀]^4- (Q= S, Se) clusters with substitutionally labile [Fe₄S₄Cl₄]^2- clusters templated by cationic surfactant molecules. The resulting novel hexagonal mesophases have parallel pore tunnels (see schematic representation) with separations of ≈35 Å, which may find applications in shape-selective electro- and photocatalysis, artificial photosynthesis, and biosensors.

Original language	English (US)
Pages (from-to)	4558-4562
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	24
DOIs	https://doi.org/10.1002/1521-3773(20001215)39:24<4558::AID-ANIE4558>3.0.CO;2-B
State	Published - Dec 15 2000

Keywords

Bioinorganic chemistry
Chalcogens
Germanium
Iron
Mesophases
Template synthesis

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/1521-3773(20001215)39:24<4558::AID-ANIE4558>3.0.CO;2-B

Cite this

Trikalitis, P. N., Bakas, T., Papaefthymiou, V., & Kanatzidis, M. G. (2000). Supramolecular assembly of hexagonal mesostructured germanium sulfide and selenide nanocomposites incorporating the biologically relevant Fe₄S₄ cluster. Angewandte Chemie - International Edition, 39(24), 4558-4562. https://doi.org/10.1002/1521-3773(20001215)39:24<4558::AID-ANIE4558>3.0.CO;2-B

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abstract = "Stable hybrid systems are generated by the reaction of adamantane [Ge4Q10]4- (Q= S, Se) clusters with substitutionally labile [Fe4S4Cl4]2- clusters templated by cationic surfactant molecules. The resulting novel hexagonal mesophases have parallel pore tunnels (see schematic representation) with separations of ≈35 {\AA}, which may find applications in shape-selective electro- and photocatalysis, artificial photosynthesis, and biosensors.",

keywords = "Bioinorganic chemistry, Chalcogens, Germanium, Iron, Mesophases, Template synthesis",

author = "Trikalitis, {Pantelis N.} and Thomas Bakas and Vasilios Papaefthymiou and Kanatzidis, {Mercouri G.}",

year = "2000",

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Trikalitis, PN, Bakas, T, Papaefthymiou, V & Kanatzidis, MG 2000, 'Supramolecular assembly of hexagonal mesostructured germanium sulfide and selenide nanocomposites incorporating the biologically relevant Fe₄S₄ cluster', Angewandte Chemie - International Edition, vol. 39, no. 24, pp. 4558-4562. https://doi.org/10.1002/1521-3773(20001215)39:24<4558::AID-ANIE4558>3.0.CO;2-B

Supramolecular assembly of hexagonal mesostructured germanium sulfide and selenide nanocomposites incorporating the biologically relevant Fe₄S₄ cluster. / Trikalitis, Pantelis N.; Bakas, Thomas; Papaefthymiou, Vasilios et al.

In: Angewandte Chemie - International Edition, Vol. 39, No. 24, 15.12.2000, p. 4558-4562.

Research output: Contribution to journal › Article › peer-review

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AU - Trikalitis, Pantelis N.

AU - Bakas, Thomas

AU - Papaefthymiou, Vasilios

AU - Kanatzidis, Mercouri G.

PY - 2000/12/15

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