Surface-enhanced Raman spectroscopy of dyes: from single molecules to the artists' canvas

Kristin L. Wustholz, Christa L. Brosseau, Francesca Casadio, Richard P. Van Duyne

Research output: Contribution to journalArticlepeer-review

105 Scopus citations

Abstract

This perspective presents recent surface-enhanced Raman spectroscopy (SERS) studies of dyes, with applications to the fields of single-molecule spectroscopy and art conservation. First we describe the development and outlook of single-molecule SERS (SMSERS). Rather than providing an exhaustive review of the literature, SMSERS experiments that we consider essential for its future development are emphasized. Shifting from single-molecule to ensemble-averaged experiments, we describe recent efforts toward SERS analysis of colorants in precious artworks. Our intention is to illustrate through these examples that the forward development of SERS is dependent upon both fundamental (e.g., SMSERS) and applied (e.g., on-the-specimen SERS of historical art objects) investigations and that the future of SERS is very bright indeed.

Original languageEnglish (US)
Pages (from-to)7350-7359
Number of pages10
JournalPhysical Chemistry Chemical Physics
Volume11
Issue number34
DOIs
StatePublished - Aug 31 2009

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Surface-enhanced Raman spectroscopy of dyes: from single molecules to the artists' canvas'. Together they form a unique fingerprint.

Cite this