Syntheses and characterization of the oxidized phthalocyanine compounds

Anna S. Gardberg, Angella E. Sprauve, James A. Ibers

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

A series of partially-oxidized phthalocyanine (pc) compounds ([Ni(pc)]3[ReO4]2·C10H 7Cl, [Cu(pc)]3[SbF6]2·C10H 7Cl, [Cu(pc)]3[AsF6]2·C10H 7Cl, [H2(pc)]3[SbF6]2·C 10H7Cl, and [Ni(pc)]3[SbF6]2·C10H 7Cl) were synthesized galvanostatically. Their structures were determined by means of conventional crystallographic methods. An improved structure of [H2(pc)]3[AsF6]2·C 10H7Cl was determined from synchrotron data. The isostructural extended structures of these compounds comprise stacked trimers of M(pc) rings with anions and disordered solvents in parallel channels. Conductivity data for [Cu(pc)]3[SbF6]2·C10H 7Cl indicate that it is a semiconductor (EA = 0.22 eV).

Original languageEnglish (US)
Pages (from-to)179-184
Number of pages6
JournalInorganica Chimica Acta
Volume328
Issue number1
DOIs
StatePublished - Jan 30 2002

Keywords

  • Crystal structures
  • Galvanostatic synthesis
  • Phthalocyanine

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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