Syntheses and structure of hydrothermally prepared CsNiX 3 (X=Cl, Br, I)

Adam D. Raw; James A. Ibers; Kenneth R. Poeppelmeier

doi:10.1016/j.jssc.2012.03.037

Syntheses and structure of hydrothermally prepared CsNiX ₃ (X=Cl, Br, I)

Adam D. Raw, James A. Ibers, Kenneth R. Poeppelmeier^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

During reinvestigation of the hydrothermal synthesis reported earlier of the compound cesium nickel phosphide, CsNiP, we arrived at a new route to the synthesis of the cesium nickel halide compounds CsNiX ₃ (X=Cl, Br, I). The method has also been shown to extend to cobalt and iron compounds. Single crystals of these compounds were synthesized in phosphoric acid in sealed autoclaves. Their structures were determined by single-crystal X-ray diffraction methods. The compounds crystallize in the hexagonal space group P6 ₃/mmc in the BaNiO ₃ structure type. The synthetic method and the resultant crystallographic details for CsNiCl ₃ are essentially identical with those reported earlier for the synthesis and structure of CsNiP.

Original language	English (US)
Pages (from-to)	34-37
Number of pages	4
Journal	Journal of Solid State Chemistry
Volume	192
DOIs	https://doi.org/10.1016/j.jssc.2012.03.037
State	Published - Aug 2012

Funding

This work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under contract no. De-AC36-08GO28308 to NREL. The center for Inverse Design is a DOE Energy Frontier Research Center. Partial funding for this research was kindly provided by the U.S. Department of Energy, Basic Energy Sciences, Chemical Sciences, Biosciences, and Geosciences Division and Division of Materials Science and Engineering Grant ERB15522 (JAI). SEM analyses were conducted in the Electron Probe Instrumentation Center (EPIC) at the Northwestern University Atomic and Nanoscale Characterization Experimental (NUANCE) Center, supported by NSF-NSEC, NSF-MRSEC, Keck Foundation, the State of Illinois, and Northwestern University. Single-crystal data were collected at the IMSERC X-ray Facility at Northwestern University, supported by the International Institute of Nanotechnology (IIN).

Keywords

Cesium nickel bromide
Cesium nickel chloride
Cesium nickel iodide
Hydrothermal synthesis
X-ray crystal structure

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.jssc.2012.03.037

Cite this

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title = "Syntheses and structure of hydrothermally prepared CsNiX 3 (X=Cl, Br, I)",

abstract = "During reinvestigation of the hydrothermal synthesis reported earlier of the compound cesium nickel phosphide, CsNiP, we arrived at a new route to the synthesis of the cesium nickel halide compounds CsNiX 3 (X=Cl, Br, I). The method has also been shown to extend to cobalt and iron compounds. Single crystals of these compounds were synthesized in phosphoric acid in sealed autoclaves. Their structures were determined by single-crystal X-ray diffraction methods. The compounds crystallize in the hexagonal space group P6 3/mmc in the BaNiO 3 structure type. The synthetic method and the resultant crystallographic details for CsNiCl 3 are essentially identical with those reported earlier for the synthesis and structure of CsNiP.",

keywords = "Cesium nickel bromide, Cesium nickel chloride, Cesium nickel iodide, Hydrothermal synthesis, X-ray crystal structure",

author = "Raw, {Adam D.} and Ibers, {James A.} and Poeppelmeier, {Kenneth R.}",

note = "Funding Information: This work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under contract no. De-AC36-08GO28308 to NREL. The center for Inverse Design is a DOE Energy Frontier Research Center. Partial funding for this research was kindly provided by the U.S. Department of Energy, Basic Energy Sciences, Chemical Sciences, Biosciences, and Geosciences Division and Division of Materials Science and Engineering Grant ERB15522 (JAI). SEM analyses were conducted in the Electron Probe Instrumentation Center (EPIC) at the Northwestern University Atomic and Nanoscale Characterization Experimental (NUANCE) Center, supported by NSF-NSEC, NSF-MRSEC, Keck Foundation, the State of Illinois, and Northwestern University. Single-crystal data were collected at the IMSERC X-ray Facility at Northwestern University, supported by the International Institute of Nanotechnology (IIN). ",

year = "2012",

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doi = "10.1016/j.jssc.2012.03.037",

language = "English (US)",

volume = "192",

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journal = "Journal of Solid State Chemistry",

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AU - Raw, Adam D.

AU - Ibers, James A.

AU - Poeppelmeier, Kenneth R.

N1 - Funding Information: This work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under contract no. De-AC36-08GO28308 to NREL. The center for Inverse Design is a DOE Energy Frontier Research Center. Partial funding for this research was kindly provided by the U.S. Department of Energy, Basic Energy Sciences, Chemical Sciences, Biosciences, and Geosciences Division and Division of Materials Science and Engineering Grant ERB15522 (JAI). SEM analyses were conducted in the Electron Probe Instrumentation Center (EPIC) at the Northwestern University Atomic and Nanoscale Characterization Experimental (NUANCE) Center, supported by NSF-NSEC, NSF-MRSEC, Keck Foundation, the State of Illinois, and Northwestern University. Single-crystal data were collected at the IMSERC X-ray Facility at Northwestern University, supported by the International Institute of Nanotechnology (IIN).

PY - 2012/8

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N2 - During reinvestigation of the hydrothermal synthesis reported earlier of the compound cesium nickel phosphide, CsNiP, we arrived at a new route to the synthesis of the cesium nickel halide compounds CsNiX 3 (X=Cl, Br, I). The method has also been shown to extend to cobalt and iron compounds. Single crystals of these compounds were synthesized in phosphoric acid in sealed autoclaves. Their structures were determined by single-crystal X-ray diffraction methods. The compounds crystallize in the hexagonal space group P6 3/mmc in the BaNiO 3 structure type. The synthetic method and the resultant crystallographic details for CsNiCl 3 are essentially identical with those reported earlier for the synthesis and structure of CsNiP.

AB - During reinvestigation of the hydrothermal synthesis reported earlier of the compound cesium nickel phosphide, CsNiP, we arrived at a new route to the synthesis of the cesium nickel halide compounds CsNiX 3 (X=Cl, Br, I). The method has also been shown to extend to cobalt and iron compounds. Single crystals of these compounds were synthesized in phosphoric acid in sealed autoclaves. Their structures were determined by single-crystal X-ray diffraction methods. The compounds crystallize in the hexagonal space group P6 3/mmc in the BaNiO 3 structure type. The synthetic method and the resultant crystallographic details for CsNiCl 3 are essentially identical with those reported earlier for the synthesis and structure of CsNiP.

KW - Cesium nickel bromide

KW - Cesium nickel chloride

KW - Cesium nickel iodide

KW - Hydrothermal synthesis

KW - X-ray crystal structure

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