Syntheses, structures, and characterization of two new rubidium cadmium(2)/zinc(2) borates: Rb3MB5O10 (M = Cd, Zn)

Hongwei Yu; Hongping Wu; Shilie Pan; Lingyun Dong; Shujun Han; Anqing Jiao; Kenneth R. Poeppelmeier

doi:10.1524/zkri.2013.1619

Syntheses, structures, and characterization of two new rubidium cadmium(2)/zinc(2) borates: Rb₃MB₅O₁₀ (M = Cd, Zn)

Hongwei Yu, Hongping Wu, Shilie Pan^*, Lingyun Dong, Shujun Han, Anqing Jiao, Kenneth R. Poeppelmeier

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Two new ternary borates, Rb₃MB₅O₁₀ (M = Zn, Cd) have been synthesized by solid-state reactions, and their structures were determined by single-crystal X-ray diffraction. They crystallize in the same monoclinic space group P2₁=n with lattice constants a = 10.449(11)Å , b = 9.414(10)Å , c = 11.690(12)Å , and β = 105.888(11)^° for Rb₃ZnB₅O₁₀, while a = 7.6391(5)Å , b =19.2304(13)Å , c = 7.6905(5)Å , and β = 116.698(4)^° for Rb₃CdB₅O ₁₀. And their crystal structures both contain the interesting two-dimension (2D) infinite [MB₅O₁₀]∞ (M = Zn, Cd) layers. However, owing to the different configurations and stacking directions of the [MB₅O₁₀]∞ (M = Zn, Cd) layers, Rb ₃ZnB₅O₁₀ and Rb₃CdB ₅O₁₀ are not isostructural. The IR spectra further confirm the presence of both BO3 and BO4 groups and UV-Vis-NIR diffuse reflectance spectra show their band gaps are 2.66 and 2.34 eV for Rb₃ZnB ₅O₁₀ and Rb₃CdB₅O₁₀, respectively.

Original language	English (US)
Pages (from-to)	444-448
Number of pages	5
Journal	Zeitschrift fur Kristallographie
Volume	288
Issue number	9
DOIs	https://doi.org/10.1524/zkri.2013.1619
State	Published - Sep 2013

Funding

Research Program of China (Grant No. 2012CB626803), the “National Natural Science Foundation of China” (Grant Nos. 21201176, U1129301, 51172277, 21101168), Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences (Grant No. KJCX2-EW-H03-03), the “One Hundred Talents Project Foundation Program” of Chinese Academy of Sciences, Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period (Grant No. 201130111), the “High Technology Research and Development Program” of Xinjiang Uygur Autonomous Region of China (Grant No. 201116143, 201315103); K.R.P. acknowledges support from NSF (Solid State Chemistry Award DMR-1005827). Acknowledgement. This work is supported by the National Key Basic

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Inorganic Chemistry

Access to Document

10.1524/zkri.2013.1619

Cite this

@article{cab109e948d34191a0a4f396186c404f,

title = "Syntheses, structures, and characterization of two new rubidium cadmium(2)/zinc(2) borates: Rb3MB5O10 (M = Cd, Zn)",

abstract = "Two new ternary borates, Rb3MB5O10 (M = Zn, Cd) have been synthesized by solid-state reactions, and their structures were determined by single-crystal X-ray diffraction. They crystallize in the same monoclinic space group P21=n with lattice constants a = 10.449(11){\AA} , b = 9.414(10){\AA} , c = 11.690(12){\AA} , and β = 105.888(11)° for Rb3ZnB5O10, while a = 7.6391(5){\AA} , b =19.2304(13){\AA} , c = 7.6905(5){\AA} , and β = 116.698(4)° for Rb3CdB5O 10. And their crystal structures both contain the interesting two-dimension (2D) infinite [MB5O10]∞ (M = Zn, Cd) layers. However, owing to the different configurations and stacking directions of the [MB5O10]∞ (M = Zn, Cd) layers, Rb 3ZnB5O10 and Rb3CdB 5O10 are not isostructural. The IR spectra further confirm the presence of both BO3 and BO4 groups and UV-Vis-NIR diffuse reflectance spectra show their band gaps are 2.66 and 2.34 eV for Rb3ZnB 5O10 and Rb3CdB5O10, respectively.",

author = "Hongwei Yu and Hongping Wu and Shilie Pan and Lingyun Dong and Shujun Han and Anqing Jiao and Poeppelmeier, {Kenneth R.}",

note = "Funding Information: Research Program of China (Grant No. 2012CB626803), the “National Natural Science Foundation of China” (Grant Nos. 21201176, U1129301, 51172277, 21101168), Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences (Grant No. KJCX2-EW-H03-03), the “One Hundred Talents Project Foundation Program” of Chinese Academy of Sciences, Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period (Grant No. 201130111), the “High Technology Research and Development Program” of Xinjiang Uygur Autonomous Region of China (Grant No. 201116143, 201315103); K.R.P. acknowledges support from NSF (Solid State Chemistry Award DMR-1005827). Funding Information: Acknowledgement. This work is supported by the National Key Basic",

year = "2013",

month = sep,

doi = "10.1524/zkri.2013.1619",

language = "English (US)",

volume = "288",

pages = "444--448",

journal = "Zeitschrift fur Kristallographie",

issn = "0044-2968",

number = "9",

}

TY - JOUR

T1 - Syntheses, structures, and characterization of two new rubidium cadmium(2)/zinc(2) borates

T2 - Rb3MB5O10 (M = Cd, Zn)

AU - Yu, Hongwei

AU - Wu, Hongping

AU - Pan, Shilie

AU - Dong, Lingyun

AU - Han, Shujun

AU - Jiao, Anqing

AU - Poeppelmeier, Kenneth R.

N1 - Funding Information: Research Program of China (Grant No. 2012CB626803), the “National Natural Science Foundation of China” (Grant Nos. 21201176, U1129301, 51172277, 21101168), Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences (Grant No. KJCX2-EW-H03-03), the “One Hundred Talents Project Foundation Program” of Chinese Academy of Sciences, Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period (Grant No. 201130111), the “High Technology Research and Development Program” of Xinjiang Uygur Autonomous Region of China (Grant No. 201116143, 201315103); K.R.P. acknowledges support from NSF (Solid State Chemistry Award DMR-1005827). Funding Information: Acknowledgement. This work is supported by the National Key Basic

PY - 2013/9

Y1 - 2013/9

N2 - Two new ternary borates, Rb3MB5O10 (M = Zn, Cd) have been synthesized by solid-state reactions, and their structures were determined by single-crystal X-ray diffraction. They crystallize in the same monoclinic space group P21=n with lattice constants a = 10.449(11)Å , b = 9.414(10)Å , c = 11.690(12)Å , and β = 105.888(11)° for Rb3ZnB5O10, while a = 7.6391(5)Å , b =19.2304(13)Å , c = 7.6905(5)Å , and β = 116.698(4)° for Rb3CdB5O 10. And their crystal structures both contain the interesting two-dimension (2D) infinite [MB5O10]∞ (M = Zn, Cd) layers. However, owing to the different configurations and stacking directions of the [MB5O10]∞ (M = Zn, Cd) layers, Rb 3ZnB5O10 and Rb3CdB 5O10 are not isostructural. The IR spectra further confirm the presence of both BO3 and BO4 groups and UV-Vis-NIR diffuse reflectance spectra show their band gaps are 2.66 and 2.34 eV for Rb3ZnB 5O10 and Rb3CdB5O10, respectively.

AB - Two new ternary borates, Rb3MB5O10 (M = Zn, Cd) have been synthesized by solid-state reactions, and their structures were determined by single-crystal X-ray diffraction. They crystallize in the same monoclinic space group P21=n with lattice constants a = 10.449(11)Å , b = 9.414(10)Å , c = 11.690(12)Å , and β = 105.888(11)° for Rb3ZnB5O10, while a = 7.6391(5)Å , b =19.2304(13)Å , c = 7.6905(5)Å , and β = 116.698(4)° for Rb3CdB5O 10. And their crystal structures both contain the interesting two-dimension (2D) infinite [MB5O10]∞ (M = Zn, Cd) layers. However, owing to the different configurations and stacking directions of the [MB5O10]∞ (M = Zn, Cd) layers, Rb 3ZnB5O10 and Rb3CdB 5O10 are not isostructural. The IR spectra further confirm the presence of both BO3 and BO4 groups and UV-Vis-NIR diffuse reflectance spectra show their band gaps are 2.66 and 2.34 eV for Rb3ZnB 5O10 and Rb3CdB5O10, respectively.

UR - http://www.scopus.com/inward/record.url?scp=84888370033&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84888370033&partnerID=8YFLogxK

U2 - 10.1524/zkri.2013.1619

DO - 10.1524/zkri.2013.1619

M3 - Article

AN - SCOPUS:84888370033

SN - 0044-2968

VL - 288

SP - 444

EP - 448

JO - Zeitschrift fur Kristallographie

JF - Zeitschrift fur Kristallographie

IS - 9

ER -

Syntheses, structures, and characterization of two new rubidium cadmium(2)/zinc(2) borates: Rb₃MB₅O₁₀ (M = Cd, Zn)

Abstract

Funding

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

CSD 927416: Experimental Crystal Structure Determination

CSD 927417: Experimental Crystal Structure Determination

Cite this

Syntheses, structures, and characterization of two new rubidium cadmium(2)/zinc(2) borates: Rb3MB5O10 (M = Cd, Zn)

Abstract

Funding

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CSD 927416: Experimental Crystal Structure Determination

CSD 927417: Experimental Crystal Structure Determination

Cite this

Syntheses, structures, and characterization of two new rubidium cadmium(2)/zinc(2) borates: Rb₃MB₅O₁₀ (M = Cd, Zn)