Synthesis and characterization of 2 × 4 tunnel structured manganese dioxides as Cathodes in Rechargeable Li, Na, and Mg batteries

Altug S. Poyraz; Calvin D. Quilty; Lisa M. Housel; Xiaobing Hu; Andrea M. Bruck; Yue Ru Li; Jiefu Yin; Bingjie Zhang; Jianping Huang; Lijun Wu; Yimei Zhu; Esther S. Takeuchi; Amy C. Marschilok; Kenneth J. Takeuchi

doi:10.1149/2.1341902jes

Synthesis and characterization of 2 × 4 tunnel structured manganese dioxides as Cathodes in Rechargeable Li, Na, and Mg batteries

Altug S. Poyraz, Calvin D. Quilty, Lisa M. Housel, Xiaobing Hu, Andrea M. Bruck, Yue Ru Li, Jiefu Yin, Bingjie Zhang, Jianping Huang, Lijun Wu, Yimei Zhu, Esther S. Takeuchi, Amy C. Marschilok, Kenneth J. Takeuchi

NUANCE - Atomic and Nanoscale Characterization Experimental Center

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Sodium containing 2 × 4 (0.46nm × 0.92nm) tunnel structured manganese dioxide (Na-2 × 4-MnO₂) nanofibers are hydrothermally synthesized. The nanofibrous Na-2 × 4-MnO₂ was thoroughly characterized using X-ray diffraction (XRD), thermogravimetric analysis (TGA), inductively coupled plasma optical emission spectroscopy (ICP-OES), N2 sorption, and electron microscopy (SEM and TEM) and is assigned a formula of Na0.25MnO₂.0.16H2O. The electrochemistry of Na-2 × 4-MnO₂ in non-aqueous Li, Na and Mg batteries is compared for the first time and first cycle delivered capacities were found to be 152mAh/g, 86mAh/g, and 307mAh/g, respectively. Characterization of the active material after electrochemical tests demonstrated that Na-2 × 4-MnO₂ preserved both its crystallographic structure and nanofibrous morphology after cycling in Na and Li cells, however, Na-2 × 4-MnO₂ lost its crystalline structure after cycling in a Mg based system.

Original language	English (US)
Pages (from-to)	A670-A678
Journal	Journal of the Electrochemical Society
Volume	166
Issue number	4
DOIs	https://doi.org/10.1149/2.1341902jes
State	Published - 2019

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films
Electrochemistry
Materials Chemistry

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1149/2.1341902jes

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Poyraz, A. S., Quilty, C. D., Housel, L. M., Hu, X., Bruck, A. M., Li, Y. R., Yin, J., Zhang, B., Huang, J., Wu, L., Zhu, Y., Takeuchi, E. S., Marschilok, A. C., & Takeuchi, K. J. (2019). Synthesis and characterization of 2 × 4 tunnel structured manganese dioxides as Cathodes in Rechargeable Li, Na, and Mg batteries. Journal of the Electrochemical Society, 166(4), A670-A678. https://doi.org/10.1149/2.1341902jes

@article{034b4d2610a7449b8d24e38011584050,

title = "Synthesis and characterization of 2 × 4 tunnel structured manganese dioxides as Cathodes in Rechargeable Li, Na, and Mg batteries",

abstract = "Sodium containing 2 × 4 (0.46nm × 0.92nm) tunnel structured manganese dioxide (Na-2 × 4-MnO2) nanofibers are hydrothermally synthesized. The nanofibrous Na-2 × 4-MnO2 was thoroughly characterized using X-ray diffraction (XRD), thermogravimetric analysis (TGA), inductively coupled plasma optical emission spectroscopy (ICP-OES), N2 sorption, and electron microscopy (SEM and TEM) and is assigned a formula of Na0.25MnO2.0.16H2O. The electrochemistry of Na-2 × 4-MnO2 in non-aqueous Li, Na and Mg batteries is compared for the first time and first cycle delivered capacities were found to be 152mAh/g, 86mAh/g, and 307mAh/g, respectively. Characterization of the active material after electrochemical tests demonstrated that Na-2 × 4-MnO2 preserved both its crystallographic structure and nanofibrous morphology after cycling in Na and Li cells, however, Na-2 × 4-MnO2 lost its crystalline structure after cycling in a Mg based system.",

author = "Poyraz, {Altug S.} and Quilty, {Calvin D.} and Housel, {Lisa M.} and Xiaobing Hu and Bruck, {Andrea M.} and Li, {Yue Ru} and Jiefu Yin and Bingjie Zhang and Jianping Huang and Lijun Wu and Yimei Zhu and Takeuchi, {Esther S.} and Marschilok, {Amy C.} and Takeuchi, {Kenneth J.}",

note = "Funding Information: This work was supported as part of the Center for Mesoscale Transport Properties, an Energy Frontier Research Center supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, under award #DE-SC0012673. A. M. B. acknowledges the support of the National Science Foundation Graduate Research Fellowship under grant No. 1109408. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Science Foundation. Publisher Copyright: {\textcopyright} 2019 The Electrochemical Society.",

year = "2019",

doi = "10.1149/2.1341902jes",

language = "English (US)",

volume = "166",

pages = "A670--A678",

journal = "Journal of the Electrochemical Society",

issn = "0013-4651",

publisher = "Electrochemical Society, Inc.",

number = "4",

}

Poyraz, AS, Quilty, CD, Housel, LM, Hu, X, Bruck, AM, Li, YR, Yin, J, Zhang, B, Huang, J, Wu, L, Zhu, Y, Takeuchi, ES, Marschilok, AC & Takeuchi, KJ 2019, 'Synthesis and characterization of 2 × 4 tunnel structured manganese dioxides as Cathodes in Rechargeable Li, Na, and Mg batteries', Journal of the Electrochemical Society, vol. 166, no. 4, pp. A670-A678. https://doi.org/10.1149/2.1341902jes

TY - JOUR

T1 - Synthesis and characterization of 2 × 4 tunnel structured manganese dioxides as Cathodes in Rechargeable Li, Na, and Mg batteries

AU - Poyraz, Altug S.

AU - Quilty, Calvin D.

AU - Housel, Lisa M.

AU - Hu, Xiaobing

AU - Bruck, Andrea M.

AU - Li, Yue Ru

AU - Yin, Jiefu

AU - Zhang, Bingjie

AU - Huang, Jianping

AU - Wu, Lijun

AU - Zhu, Yimei

AU - Takeuchi, Esther S.

AU - Marschilok, Amy C.

AU - Takeuchi, Kenneth J.

N1 - Funding Information: This work was supported as part of the Center for Mesoscale Transport Properties, an Energy Frontier Research Center supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, under award #DE-SC0012673. A. M. B. acknowledges the support of the National Science Foundation Graduate Research Fellowship under grant No. 1109408. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Science Foundation. Publisher Copyright: © 2019 The Electrochemical Society.

PY - 2019

Y1 - 2019

N2 - Sodium containing 2 × 4 (0.46nm × 0.92nm) tunnel structured manganese dioxide (Na-2 × 4-MnO2) nanofibers are hydrothermally synthesized. The nanofibrous Na-2 × 4-MnO2 was thoroughly characterized using X-ray diffraction (XRD), thermogravimetric analysis (TGA), inductively coupled plasma optical emission spectroscopy (ICP-OES), N2 sorption, and electron microscopy (SEM and TEM) and is assigned a formula of Na0.25MnO2.0.16H2O. The electrochemistry of Na-2 × 4-MnO2 in non-aqueous Li, Na and Mg batteries is compared for the first time and first cycle delivered capacities were found to be 152mAh/g, 86mAh/g, and 307mAh/g, respectively. Characterization of the active material after electrochemical tests demonstrated that Na-2 × 4-MnO2 preserved both its crystallographic structure and nanofibrous morphology after cycling in Na and Li cells, however, Na-2 × 4-MnO2 lost its crystalline structure after cycling in a Mg based system.

AB - Sodium containing 2 × 4 (0.46nm × 0.92nm) tunnel structured manganese dioxide (Na-2 × 4-MnO2) nanofibers are hydrothermally synthesized. The nanofibrous Na-2 × 4-MnO2 was thoroughly characterized using X-ray diffraction (XRD), thermogravimetric analysis (TGA), inductively coupled plasma optical emission spectroscopy (ICP-OES), N2 sorption, and electron microscopy (SEM and TEM) and is assigned a formula of Na0.25MnO2.0.16H2O. The electrochemistry of Na-2 × 4-MnO2 in non-aqueous Li, Na and Mg batteries is compared for the first time and first cycle delivered capacities were found to be 152mAh/g, 86mAh/g, and 307mAh/g, respectively. Characterization of the active material after electrochemical tests demonstrated that Na-2 × 4-MnO2 preserved both its crystallographic structure and nanofibrous morphology after cycling in Na and Li cells, however, Na-2 × 4-MnO2 lost its crystalline structure after cycling in a Mg based system.

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U2 - 10.1149/2.1341902jes

DO - 10.1149/2.1341902jes

M3 - Article

AN - SCOPUS:85063088082

VL - 166

SP - A670-A678

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

SN - 0013-4651

IS - 4

ER -

Synthesis and characterization of 2 × 4 tunnel structured manganese dioxides as Cathodes in Rechargeable Li, Na, and Mg batteries

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