Abstract
Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.
Original language | English (US) |
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Pages (from-to) | 2797-2800 |
Number of pages | 4 |
Journal | Polyhedron |
Volume | 13 |
Issue number | 19 |
DOIs | |
State | Published - 1994 |
Funding
Acknowledgements-Financials upport from NASA is gratefullya cknowledgedM. .G.K. is an A. P. Sloan Foundation Fellow (1991-93)a nd a Camille and Henry Drey-fuss Teacher-Scholar( 1993-95).P artial support from the Donors of the Petroleum ResearchF und is also acknowledgedT. he X-ray instrumentationu sed in this work wasp urchasedin part with funds from NSF Grant CHE-8908088.W e also thank the Center for Electron Optics at Michigan StateU niversity for use of the electron microscopyf acilities.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry