Abstract
Crystals of the unusual oxyfluoroselenide La3NbSe2O4F2 were obtained during the exploration of the quaternary La/Nb/Cu/Se system. Oxygen was extracted from the silica tube, while fluorine was present as a minor impurity in the La powder. The compound crystallizes in space group D162h-Pnma of the orthorhombic system with four formula units in a cell with dimensions: a = 11.290(4), b = 4.001(1), and c = 18.062(4) Å (T = 113 K). The structure has been determined by single-crystal X-ray methods. The presence of F in the crystals was confirmed by windowless EDAX measurements. The two F sites were distinguished from the four O sites from a combination of the X-ray refinement and a bond-valence parameter calculation made with the program EUTAX. In the structure the Nb atom is octahedrally coordinated while each of the three independent La atoms is in a tricapped trigonal prism. The Nb atom is bound to one Se atom and five O atoms while the three La sites are coordinated by various combinations of Se, O, and F atoms. The NbO5Se octahedra corner share and the LaSexOyFz tricapped trigonal prisms face share in the b direction.
Original language | English (US) |
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Pages (from-to) | 547-553 |
Number of pages | 7 |
Journal | Journal of Solid State Chemistry |
Volume | 107 |
Issue number | 2 |
DOIs | |
State | Published - Dec 1993 |
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry