Synthesis and Characterization of Silver(I) Pyrazolylmethylpyridine Complexes and Their Implementation as Metallic Silver Thin Film Precursors

Irene Bassanetti; Christina P. Twist; Myung-Gil Kim; Afif M. Seyam; Hassan S. Bazzi; Q Jane Wang; Yip-Wah Chung; Luciano Marchio; Massimiliano Delferro; Tobin J. Marks

doi:10.1021/ic500321w

Synthesis and Characterization of Silver(I) Pyrazolylmethylpyridine Complexes and Their Implementation as Metallic Silver Thin Film Precursors

Irene Bassanetti, Christina P. Twist, Myung-Gil Kim, Afif M. Seyam, Hassan S. Bazzi, Q Jane Wang, Yip-Wah Chung, Luciano Marchio, Massimiliano Delferro, Tobin J. Marks

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Synthesis, structural, and spectroscopic characterization and DFT investigation of a series of light- and air-stable silver(I) pyrazolylmethylpyridine complexes is reported. The resulting polycrystalline cubic-phase Ag films contain negligible amounts of extraneous contamination. The results of the wear measurements indicate a significant reduction in wear (∼ 88%) at optimized Ag complex concentrations. Enhanced wear performance is attributed to facile shearing of Ag metal deposited in the contact region, which results from thermolysis of the silver complex

Original language	English
Pages (from-to)	4629-4638
Journal	Inorganic Chemistry
Volume	53
DOIs	https://doi.org/10.1021/ic500321w
State	Published - 2014

Access to Document

10.1021/ic500321w

Cite this

@article{72d12befc26c426bbc960897dbe4b127,

title = "Synthesis and Characterization of Silver(I) Pyrazolylmethylpyridine Complexes and Their Implementation as Metallic Silver Thin Film Precursors",

abstract = "Synthesis, structural, and spectroscopic characterization and DFT investigation of a series of light- and air-stable silver(I) pyrazolylmethylpyridine complexes is reported. The resulting polycrystalline cubic-phase Ag films contain negligible amounts of extraneous contamination. The results of the wear measurements indicate a significant reduction in wear (∼ 88%) at optimized Ag complex concentrations. Enhanced wear performance is attributed to facile shearing of Ag metal deposited in the contact region, which results from thermolysis of the silver complex",

author = "Irene Bassanetti and Twist, {Christina P.} and Myung-Gil Kim and Seyam, {Afif M.} and Bazzi, {Hassan S.} and Wang, {Q Jane} and Yip-Wah Chung and Luciano Marchio and Massimiliano Delferro and Marks, {Tobin J.}",

year = "2014",

doi = "10.1021/ic500321w",

language = "English",

volume = "53",

pages = "4629--4638",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

}

TY - JOUR

T1 - Synthesis and Characterization of Silver(I) Pyrazolylmethylpyridine Complexes and Their Implementation as Metallic Silver Thin Film Precursors

AU - Bassanetti, Irene

AU - Twist, Christina P.

AU - Kim, Myung-Gil

AU - Seyam, Afif M.

AU - Bazzi, Hassan S.

AU - Wang, Q Jane

AU - Chung, Yip-Wah

AU - Marchio, Luciano

AU - Delferro, Massimiliano

AU - Marks, Tobin J.

PY - 2014

Y1 - 2014

N2 - Synthesis, structural, and spectroscopic characterization and DFT investigation of a series of light- and air-stable silver(I) pyrazolylmethylpyridine complexes is reported. The resulting polycrystalline cubic-phase Ag films contain negligible amounts of extraneous contamination. The results of the wear measurements indicate a significant reduction in wear (∼ 88%) at optimized Ag complex concentrations. Enhanced wear performance is attributed to facile shearing of Ag metal deposited in the contact region, which results from thermolysis of the silver complex

AB - Synthesis, structural, and spectroscopic characterization and DFT investigation of a series of light- and air-stable silver(I) pyrazolylmethylpyridine complexes is reported. The resulting polycrystalline cubic-phase Ag films contain negligible amounts of extraneous contamination. The results of the wear measurements indicate a significant reduction in wear (∼ 88%) at optimized Ag complex concentrations. Enhanced wear performance is attributed to facile shearing of Ag metal deposited in the contact region, which results from thermolysis of the silver complex

U2 - 10.1021/ic500321w

DO - 10.1021/ic500321w

M3 - Article

C2 - 24745760

SN - 0020-1669

VL - 53

SP - 4629

EP - 4638

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -

Synthesis and Characterization of Silver(I) Pyrazolylmethylpyridine Complexes and Their Implementation as Metallic Silver Thin Film Precursors

Abstract

Access to Document

Fingerprint

Cite this