Synthesis and charge-dependent binding affinity of a new redox-active polymeric ligand

Alan M. Allgeier; Chad A Mirkin

doi:10.1021/om970023v

Synthesis and charge-dependent binding affinity of a new redox-active polymeric ligand

Alan M. Allgeier, Chad A Mirkin^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The synthesis and characterization of a new, polymeric, redox-active ligand with switchable binding affinities for transition metals are reported. Polymer 2 is based on p-ferrocenylphenyl acrylate and complexes the (η⁵-C₅Me₅)Ru⁺ fragment. Oxidation of the polymeric ligand changes its binding constant for Ru by over two orders of magnitude.

Original language	English (US)
Pages (from-to)	3071-3073
Number of pages	3
Journal	Organometallics
Volume	16
Issue number	13
DOIs	https://doi.org/10.1021/om970023v
State	Published - Jun 24 1997

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om970023v

Cite this

@article{82e0a20f47ac4a4fa7679ce0524a286e,

title = "Synthesis and charge-dependent binding affinity of a new redox-active polymeric ligand",

abstract = "The synthesis and characterization of a new, polymeric, redox-active ligand with switchable binding affinities for transition metals are reported. Polymer 2 is based on p-ferrocenylphenyl acrylate and complexes the (η5-C5Me5)Ru+ fragment. Oxidation of the polymeric ligand changes its binding constant for Ru by over two orders of magnitude.",

author = "Allgeier, {Alan M.} and Mirkin, {Chad A}",

year = "1997",

month = jun,

day = "24",

doi = "10.1021/om970023v",

language = "English (US)",

volume = "16",

pages = "3071--3073",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Synthesis and charge-dependent binding affinity of a new redox-active polymeric ligand

AU - Allgeier, Alan M.

AU - Mirkin, Chad A

PY - 1997/6/24

Y1 - 1997/6/24

N2 - The synthesis and characterization of a new, polymeric, redox-active ligand with switchable binding affinities for transition metals are reported. Polymer 2 is based on p-ferrocenylphenyl acrylate and complexes the (η5-C5Me5)Ru+ fragment. Oxidation of the polymeric ligand changes its binding constant for Ru by over two orders of magnitude.

AB - The synthesis and characterization of a new, polymeric, redox-active ligand with switchable binding affinities for transition metals are reported. Polymer 2 is based on p-ferrocenylphenyl acrylate and complexes the (η5-C5Me5)Ru+ fragment. Oxidation of the polymeric ligand changes its binding constant for Ru by over two orders of magnitude.

UR - http://www.scopus.com/inward/record.url?scp=0344623991&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0344623991&partnerID=8YFLogxK

U2 - 10.1021/om970023v

DO - 10.1021/om970023v

M3 - Article

AN - SCOPUS:0344623991

SN - 0276-7333

VL - 16

SP - 3071

EP - 3073

JO - Organometallics

JF - Organometallics

IS - 13

ER -

Synthesis and charge-dependent binding affinity of a new redox-active polymeric ligand

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this