Synthesis and Crystal Structure of Cs2U2(P2Se9)(Se2)2

Adel Mesbah, Jai Prakash, Jessica C. Beard, Sébastien Lebègue, James A. Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticle

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Abstract

Black single crystals of Cs2U2(P2Se9)(Se2)2 were synthesized at 1023 K by a solid-state reaction. Its structure was determined by single-crystal X-ray diffraction methods. The compound is isostructural with Rb2U2(P2Se9)(Se2)2 and Cs2Th2(P2Se9)(Se2)2 compounds, and crystallizes in the orthorhombic space group Pbca. Cs2U2(P2Se9)(Se2)2 displays a three-dimensional structure comprising USe9 polyhedra connected via the Se2 2– and P2Se9 species with channels filled by Cs atoms. From electronic structure calculations the compound is found to be a metal with a ferromagnetic arrangement of the magnetic moments.

Original languageEnglish (US)
Pages (from-to)1480-1484
Number of pages5
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume644
Issue number22
DOIs
Publication statusPublished - Nov 30 2018

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Keywords

  • Crystal structure
  • Electronic structure
  • Solid-state synthesis
  • Uranium selenophosphate

ASJC Scopus subject areas

  • Inorganic Chemistry

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