Synthesis and metalation of catechol-functionalized porous organic polymers

Mitchell H. Weston, Omar K. Farha*, Brad G. Hauser, Joseph T. Hupp, Sonbinh T. Nguyen

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

94 Scopus citations

Abstract

Robust catechol-functionalized porous organic polymers (POPs) with tunable porosities (560-1050 m2/g) and degrees of functionalization were synthesized using a cobaltcatalyzed acetylene trimerization (CCAT) strategy. Post-synthesis metalation can be readily carried out with a wide range of metal precursors (CuII, MgII, and MnII salts and complexes), resulting in metalated POPs with enhanced heat of hydrogen adsorptions compared to the starting nonmetalated materials.

Original languageEnglish (US)
Pages (from-to)1292-1296
Number of pages5
JournalChemistry of Materials
Volume24
Issue number7
DOIs
StatePublished - Apr 10 2012

Keywords

  • Hydrogen storage
  • Metal catecholates
  • Porous organic polymers

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

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