Synthesis and photovoltaic effect in dithieno[2,3-d:2′,3′- d′]benzo[1,2-b:4,5-b′]dithiophene-based conjugated polymers

Hae Jung Son; Luyao Lu; Wei Chen; Tao Xu; Tianyue Zheng; Bridget Carsten; Joseph Strzalka; Seth B. Darling; Lin X Chen; Luping Yu

doi:10.1002/adma.201204238

Synthesis and photovoltaic effect in dithieno[2,3-d:2′,3′- d′]benzo[1,2-b:4,5-b′]dithiophene-based conjugated polymers

Hae Jung Son, Luyao Lu, Wei Chen, Tao Xu, Tianyue Zheng, Bridget Carsten, Joseph Strzalka, Seth B. Darling, Lin X Chen, Luping Yu^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

173 Scopus citations

Abstract

Conjugated polymers based on a heteroacene, 3,7-dialkyl-dithieno[2,3-d: 2′,3′-d′]benzo[1,2-b:4,5-b′]dithiophene (DBD), are synthesized. These polymers show broad UV-vis absorption with energy bandgaps below 1.7 eV. PTDBD2, showing good miscibility in a polymer/phenyl-C71-butyric acid methyl ester (PC₇₁BM) blend film, achieves a power conversion efficiency (PCE) of 7.6%. The results indicate that copolymers containing DBD are promising candidates for high-performance organic solar cells.

Original language	English (US)
Pages (from-to)	838-843
Number of pages	6
Journal	Advanced Materials
Volume	25
Issue number	6
DOIs	https://doi.org/10.1002/adma.201204238
State	Published - Feb 13 2013

Keywords

acene
bulk heterojunctions
polymer solar cells

ASJC Scopus subject areas

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1002/adma.201204238

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@article{7ff9dea8992f48cf967f692b431149c4,

title = "Synthesis and photovoltaic effect in dithieno[2,3-d:2′,3′- d′]benzo[1,2-b:4,5-b′]dithiophene-based conjugated polymers",

abstract = "Conjugated polymers based on a heteroacene, 3,7-dialkyl-dithieno[2,3-d: 2′,3′-d′]benzo[1,2-b:4,5-b′]dithiophene (DBD), are synthesized. These polymers show broad UV-vis absorption with energy bandgaps below 1.7 eV. PTDBD2, showing good miscibility in a polymer/phenyl-C71-butyric acid methyl ester (PC71BM) blend film, achieves a power conversion efficiency (PCE) of 7.6%. The results indicate that copolymers containing DBD are promising candidates for high-performance organic solar cells.",

keywords = "acene, bulk heterojunctions, polymer solar cells",

author = "Son, {Hae Jung} and Luyao Lu and Wei Chen and Tao Xu and Tianyue Zheng and Bridget Carsten and Joseph Strzalka and Darling, {Seth B.} and Chen, {Lin X} and Luping Yu",

year = "2013",

month = feb,

day = "13",

doi = "10.1002/adma.201204238",

language = "English (US)",

volume = "25",

pages = "838--843",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-VCH Verlag",

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}

TY - JOUR

T1 - Synthesis and photovoltaic effect in dithieno[2,3-d:2′,3′- d′]benzo[1,2-b:4,5-b′]dithiophene-based conjugated polymers

AU - Son, Hae Jung

AU - Lu, Luyao

AU - Chen, Wei

AU - Xu, Tao

AU - Zheng, Tianyue

AU - Carsten, Bridget

AU - Strzalka, Joseph

AU - Darling, Seth B.

AU - Chen, Lin X

AU - Yu, Luping

PY - 2013/2/13

Y1 - 2013/2/13

N2 - Conjugated polymers based on a heteroacene, 3,7-dialkyl-dithieno[2,3-d: 2′,3′-d′]benzo[1,2-b:4,5-b′]dithiophene (DBD), are synthesized. These polymers show broad UV-vis absorption with energy bandgaps below 1.7 eV. PTDBD2, showing good miscibility in a polymer/phenyl-C71-butyric acid methyl ester (PC71BM) blend film, achieves a power conversion efficiency (PCE) of 7.6%. The results indicate that copolymers containing DBD are promising candidates for high-performance organic solar cells.

AB - Conjugated polymers based on a heteroacene, 3,7-dialkyl-dithieno[2,3-d: 2′,3′-d′]benzo[1,2-b:4,5-b′]dithiophene (DBD), are synthesized. These polymers show broad UV-vis absorption with energy bandgaps below 1.7 eV. PTDBD2, showing good miscibility in a polymer/phenyl-C71-butyric acid methyl ester (PC71BM) blend film, achieves a power conversion efficiency (PCE) of 7.6%. The results indicate that copolymers containing DBD are promising candidates for high-performance organic solar cells.

KW - acene

KW - bulk heterojunctions

KW - polymer solar cells

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DO - 10.1002/adma.201204238

M3 - Article

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SN - 0935-9648

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SP - 838

EP - 843

JO - Advanced Materials

JF - Advanced Materials

IS - 6

ER -

Synthesis and photovoltaic effect in dithieno[2,3-d:2′,3′- d′]benzo[1,2-b:4,5-b′]dithiophene-based conjugated polymers

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

Access to Document

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