Synthesis and properties of boron(III)-coordinated subbacteriochlorins

Shin Ya Hayashi; Eiji Tsurumaki; Yasuhide Inokuma; Pyosang Kim; Young Mo Sung; Dongho Kim; Atsuhiro Osuka

doi:10.1021/ja200669a

Synthesis and properties of boron(III)-coordinated subbacteriochlorins

Shin Ya Hayashi, Eiji Tsurumaki, Yasuhide Inokuma, Pyosang Kim, Young Mo Sung, Dongho Kim^*, Atsuhiro Osuka

^*Corresponding author for this work

Chemistry

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36 Scopus citations

Abstract

Subbacteriochlorins, which were prepared via hydrogenation of subporphyrins with Raney nickel, are modestly aromatic due to 14π-diazaannulenic circuit and exhibit characteristic blue-shifted Soret-like bands, intensified fluorescence spectra, and high oxidation potentials.

Original language	English (US)
Pages (from-to)	4254-4256
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	133
Issue number	12
DOIs	https://doi.org/10.1021/ja200669a
State	Published - Mar 30 2011

Funding

ASJC Scopus subject areas

General Chemistry
Biochemistry
Catalysis
Colloid and Surface Chemistry

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10.1021/ja200669a

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title = "Synthesis and properties of boron(III)-coordinated subbacteriochlorins",

abstract = "Subbacteriochlorins, which were prepared via hydrogenation of subporphyrins with Raney nickel, are modestly aromatic due to 14π-diazaannulenic circuit and exhibit characteristic blue-shifted Soret-like bands, intensified fluorescence spectra, and high oxidation potentials.",

author = "Hayashi, {Shin Ya} and Eiji Tsurumaki and Yasuhide Inokuma and Pyosang Kim and Sung, {Young Mo} and Dongho Kim and Atsuhiro Osuka",

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AU - Hayashi, Shin Ya

AU - Tsurumaki, Eiji

AU - Inokuma, Yasuhide

AU - Kim, Pyosang

AU - Sung, Young Mo

AU - Kim, Dongho

AU - Osuka, Atsuhiro

PY - 2011/3/30

Y1 - 2011/3/30

N2 - Subbacteriochlorins, which were prepared via hydrogenation of subporphyrins with Raney nickel, are modestly aromatic due to 14π-diazaannulenic circuit and exhibit characteristic blue-shifted Soret-like bands, intensified fluorescence spectra, and high oxidation potentials.

AB - Subbacteriochlorins, which were prepared via hydrogenation of subporphyrins with Raney nickel, are modestly aromatic due to 14π-diazaannulenic circuit and exhibit characteristic blue-shifted Soret-like bands, intensified fluorescence spectra, and high oxidation potentials.

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Synthesis and properties of boron(III)-coordinated subbacteriochlorins

Abstract

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ASJC Scopus subject areas

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