Synthesis and structure of CsCu3TiSe4

Fu Qiang Huang, Jiyong Yao, Jianghua Yang, James A. Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticle

1 Scopus citations

Abstract

The compound CsCu3TiSe4 has been synthesized by the reaction of the elements in a Cs2Se3 flux at 923 K. CsCu3TiSe4 crystallizes in a new structure type with two formula units in space group P21/m of the monoclinic system. The structure comprises two-dimensional 2[ C u3 TiS e4- ] layers separated by Cs atoms. Each 2[ C u3 TiS e4- ] layer is built from CuSe4 and TiSe4 tetrahedra.

Original languageEnglish (US)
Pages (from-to)38-41
Number of pages4
JournalJournal of Alloys and Compounds
Volume462
Issue number1-2
DOIs
StatePublished - Aug 25 2008

Keywords

  • Cesium copper titanium selenide
  • Layer structure
  • Synthesis
  • X-ray structure

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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