Synthesis and structure of na2Cu2ZrS4

Michael F. Mansuetto; James A. Ibers

doi:10.1006/jssc.1995.1242

Synthesis and structure of na₂Cu₂ZrS₄

Michael F. Mansuetto, James A. Ibers

Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The new compound Na₂Cu₂ZrS₄ has been synthesized through direct reaction of the elements with an Na₂S_n flux at 375°C. The structure has been determined by single-crystal X-ray methods. The compound crystallizes in space group C³_2h − C2/m of the monoclinic system with two formula units in a cell of dimensions a = 13.657(9), b = 3.720(3), c = 7.025(5) Å β = 112.44(3)deg; (T = 113 K). The structure is composed of ²_∞ [Cu₂ZrS₄^2-] layers separated by Na⁺ cations. A ²_∞ [Cu₂ZrS₄²⁻] layer is composed of pairs of CuS₄ tetrahedra alternating with ZrS₆ octahedra.

Original language	English (US)
Pages (from-to)	30-33
Number of pages	4
Journal	Journal of Solid State Chemistry
Volume	117
Issue number	1
DOIs	https://doi.org/10.1006/jssc.1995.1242
State	Published - Jun 1995

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1006/jssc.1995.1242

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title = "Synthesis and structure of na2Cu2ZrS4",

abstract = "The new compound Na2Cu2ZrS4 has been synthesized through direct reaction of the elements with an Na2Sn flux at 375°C. The structure has been determined by single-crystal X-ray methods. The compound crystallizes in space group C32h − C2/m of the monoclinic system with two formula units in a cell of dimensions a = 13.657(9), b = 3.720(3), c = 7.025(5) {\AA} β = 112.44(3)deg; (T = 113 K). The structure is composed of 2∞ [Cu2ZrS42-] layers separated by Na+ cations. A 2∞ [Cu2ZrS42−] layer is composed of pairs of CuS4 tetrahedra alternating with ZrS6 octahedra.",

author = "Mansuetto, {Michael F.} and Ibers, {James A.}",

year = "1995",

month = jun,

doi = "10.1006/jssc.1995.1242",

language = "English (US)",

volume = "117",

pages = "30--33",

journal = "Journal of Solid State Chemistry",

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TY - JOUR

T1 - Synthesis and structure of na2Cu2ZrS4

AU - Mansuetto, Michael F.

AU - Ibers, James A.

PY - 1995/6

Y1 - 1995/6

N2 - The new compound Na2Cu2ZrS4 has been synthesized through direct reaction of the elements with an Na2Sn flux at 375°C. The structure has been determined by single-crystal X-ray methods. The compound crystallizes in space group C32h − C2/m of the monoclinic system with two formula units in a cell of dimensions a = 13.657(9), b = 3.720(3), c = 7.025(5) Å β = 112.44(3)deg; (T = 113 K). The structure is composed of 2∞ [Cu2ZrS42-] layers separated by Na+ cations. A 2∞ [Cu2ZrS42−] layer is composed of pairs of CuS4 tetrahedra alternating with ZrS6 octahedra.

AB - The new compound Na2Cu2ZrS4 has been synthesized through direct reaction of the elements with an Na2Sn flux at 375°C. The structure has been determined by single-crystal X-ray methods. The compound crystallizes in space group C32h − C2/m of the monoclinic system with two formula units in a cell of dimensions a = 13.657(9), b = 3.720(3), c = 7.025(5) Å β = 112.44(3)deg; (T = 113 K). The structure is composed of 2∞ [Cu2ZrS42-] layers separated by Na+ cations. A 2∞ [Cu2ZrS42−] layer is composed of pairs of CuS4 tetrahedra alternating with ZrS6 octahedra.

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Synthesis and structure of na₂Cu₂ZrS₄

Abstract

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