Synthesis and structure of na2Cu2ZrS4

Michael F. Mansuetto, James A. Ibers

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

The new compound Na2Cu2ZrS4 has been synthesized through direct reaction of the elements with an Na2Sn flux at 375°C. The structure has been determined by single-crystal X-ray methods. The compound crystallizes in space group C32h − C2/m of the monoclinic system with two formula units in a cell of dimensions a = 13.657(9), b = 3.720(3), c = 7.025(5) Å β = 112.44(3)deg; (T = 113 K). The structure is composed of 2 [Cu2ZrS42-] layers separated by Na+ cations. A 2 [Cu2ZrS42−] layer is composed of pairs of CuS4 tetrahedra alternating with ZrS6 octahedra.

Original languageEnglish (US)
Pages (from-to)30-33
Number of pages4
JournalJournal of Solid State Chemistry
Volume117
Issue number1
DOIs
StatePublished - Jun 1995

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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