Synthesis and structure of the [(UO2)S4]6- anion: A cation-stabilized uranyl sulfide

Matthew D. Ward, Jordan M. Klingsporn, James A Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticle

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Abstract

The new uranyl sulfide anion [(UO2)S4]6- has been synthesized and characterized as a cation-stabilized anion in the compound Na2Ba2(UO2)S4. This compound was synthesized at 873 K from the solid-state reaction of uranium, Na2O2, BaS, and sulfur. The coordination about the U 6+ center in [(UO2)S4]6- is square bipyramidal with the uranyl O atoms 180 apart and four equatorial S atoms. The Na+ and Ba2+ cations form interactions with the uranyl O atoms. Despite the inherent difficulties involved in the synthesis of complex uranium oxysulfides, it is demonstrated that under the right reaction conditions the UO2 2+ species can be produced in situ and result in totally new chalcogen derivatives.

Original languageEnglish (US)
Pages (from-to)10220-10222
Number of pages3
JournalInorganic Chemistry
Volume52
Issue number18
DOIs
Publication statusPublished - Sep 16 2013

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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