Synthesis and X-ray crystal structure of [(C5Ph 5)CrCl(μ-Cl)2Tl]2: An example of the rare M-X-Tli linkage (X = halide)

K. Brian Davis; T. David Harris; Michael P. Castellani; James A. Golen; Arnold L. Rheingold

doi:10.1021/om070231f

Synthesis and X-ray crystal structure of [(C₅Ph ₅)CrCl(μ-Cl)₂Tl]₂: An example of the rare M-X-Tlⁱ linkage (X = halide)

K. Brian Davis, T. David Harris, Michael P. Castellani^*, James A. Golen, Arnold L. Rheingold

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Reaction of solid TlCl with [(C₅Ph₅)CrCl(μ-Cl)] ₂ in CH₂Cl₂ solvent yields the dimeric complex [(C₅Ph₅)CrCl(μ-Cl)₂-Tl]₂ in 80% isolated yield. The C₅H₅ and C₅Me₅ analogues do not react with TlCl, suggesting a steric basis for the reaction of the C₅Ph₅ material.

Original language	English (US)
Pages (from-to)	4843-4845
Number of pages	3
Journal	Organometallics
Volume	26
Issue number	19
DOIs	https://doi.org/10.1021/om070231f
State	Published - Sep 10 2007

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Synthesis and X-ray crystal structure of [(C5Ph 5)CrCl(μ-Cl)2Tl]2: An example of the rare M-X-Tli linkage (X = halide)",

abstract = "Reaction of solid TlCl with [(C5Ph5)CrCl(μ-Cl)] 2 in CH2Cl2 solvent yields the dimeric complex [(C5Ph5)CrCl(μ-Cl)2-Tl]2 in 80% isolated yield. The C5H5 and C5Me5 analogues do not react with TlCl, suggesting a steric basis for the reaction of the C5Ph5 material.",

author = "Davis, {K. Brian} and Harris, {T. David} and Castellani, {Michael P.} and Golen, {James A.} and Rheingold, {Arnold L.}",

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journal = "Organometallics",

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T2 - An example of the rare M-X-Tli linkage (X = halide)

AU - Davis, K. Brian

AU - Harris, T. David

AU - Castellani, Michael P.

AU - Golen, James A.

AU - Rheingold, Arnold L.

PY - 2007/9/10

Y1 - 2007/9/10

N2 - Reaction of solid TlCl with [(C5Ph5)CrCl(μ-Cl)] 2 in CH2Cl2 solvent yields the dimeric complex [(C5Ph5)CrCl(μ-Cl)2-Tl]2 in 80% isolated yield. The C5H5 and C5Me5 analogues do not react with TlCl, suggesting a steric basis for the reaction of the C5Ph5 material.

AB - Reaction of solid TlCl with [(C5Ph5)CrCl(μ-Cl)] 2 in CH2Cl2 solvent yields the dimeric complex [(C5Ph5)CrCl(μ-Cl)2-Tl]2 in 80% isolated yield. The C5H5 and C5Me5 analogues do not react with TlCl, suggesting a steric basis for the reaction of the C5Ph5 material.

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Synthesis and X-ray crystal structure of [(C₅Ph ₅)CrCl(μ-Cl)₂Tl]₂: An example of the rare M-X-Tlⁱ linkage (X = halide)

Abstract

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