Synthesis, characterization, and x-ray structure of the ruthenium “picnic-basket” porphyrins

James P. Collman*, John I. Brauman, Jeffrey P. Fitzgerald, Philip D. Hampton, Yoshinori Naruta, John W. Sparapany, James A Ibers

*Corresponding author for this work

Research output: Contribution to journalArticle

81 Scopus citations

Abstract

The synthesis and characterization of a new class of sterically protected porphyrins, the “picnic-basket” porphyrins, are presented. These tetraarylporphyrins, which were prepared as cytochrome P-450 active-site analogues, bear a rigid superstructure on one face of the porphyrin macrocycle. The cavity defined by the appended superstructure may be readily varied in size, chirality, and functionality. In addition, the synthesis and characterization, including an X-ray structure, of several ruthenium picnic-basket porphyrin carbonyl complexes are reported. The regiochemistry of axial ligation in these ruthenium derivatives has been determined by NMR spectroscopy.

Original languageEnglish (US)
Pages (from-to)3477-3486
Number of pages10
JournalJournal of the American Chemical Society
Volume110
Issue number11
DOIs
StatePublished - Jan 1 1988

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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    Collman, J. P., Brauman, J. I., Fitzgerald, J. P., Hampton, P. D., Naruta, Y., Sparapany, J. W., & Ibers, J. A. (1988). Synthesis, characterization, and x-ray structure of the ruthenium “picnic-basket” porphyrins. Journal of the American Chemical Society, 110(11), 3477-3486. https://doi.org/10.1021/ja00219a023