Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14

Shilie Pan; Jared P. Smit; Michael R. Marvel; Evan S. Stampler; Jacob M. Haag; Jaewook Baek; P. Shiv Halasyamani; Kenneth R. Poeppelmeier

doi:10.1016/j.jssc.2008.05.008

Synthesis, crystal structure, and nonlinear optical properties of Bi₂Cu₅B₄O₁₄

Shilie Pan^*, Jared P. Smit, Michael R. Marvel, Evan S. Stampler, Jacob M. Haag, Jaewook Baek, P. Shiv Halasyamani, Kenneth R. Poeppelmeier

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Bi₂Cu₅B₄O₁₄ crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a=10.1381(11) Å, b=9.3917(11) Å, c=3.4566(4) Å, α=105.570(2)°, β=92.275(2)°, γ=107.783(2)°, Z=1 and R₁=0.0401 and wR₂=0.0980. It is a layered structure that is built up from sheets of rectangular CuO₄ and trigonal BO₃ groups. The sheets are connected by infinite chains of edge shared BiO₆ polyhedra that intersect the bc plane at an angle slightly greater than 90°. The second-harmonic generation efficiency of Bi₂Cu₅B₄O₁₄, using 1064 nm radiation, is about one half times that of KH₂PO₄.

Original language	English (US)
Pages (from-to)	2087-2091
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	181
Issue number	8
DOIs	https://doi.org/10.1016/j.jssc.2008.05.008
State	Published - Aug 2008

Keywords

Crystal growth
Crystal structure
Nonlinear optical properties
Oxide

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.jssc.2008.05.008

Cite this

@article{8ec0bc0568334777aa910801923d69c7,

title = "Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14",

abstract = "Bi2Cu5B4O14 crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a=10.1381(11) {\AA}, b=9.3917(11) {\AA}, c=3.4566(4) {\AA}, α=105.570(2)°, β=92.275(2)°, γ=107.783(2)°, Z=1 and R1=0.0401 and wR2=0.0980. It is a layered structure that is built up from sheets of rectangular CuO4 and trigonal BO3 groups. The sheets are connected by infinite chains of edge shared BiO6 polyhedra that intersect the bc plane at an angle slightly greater than 90°. The second-harmonic generation efficiency of Bi2Cu5B4O14, using 1064 nm radiation, is about one half times that of KH2PO4.",

keywords = "Crystal growth, Crystal structure, Nonlinear optical properties, Oxide",

author = "Shilie Pan and Smit, {Jared P.} and Marvel, {Michael R.} and Stampler, {Evan S.} and Haag, {Jacob M.} and Jaewook Baek and Halasyamani, {P. Shiv} and Poeppelmeier, {Kenneth R.}",

note = "Funding Information: The authors thank Charlotte L. Stern for assistance with crystallographic measurements. The authors gratefully acknowledge the financial support from the National Science Foundation (Solid State Chemistry Award nos. DMR-0312136 and DMR-0604454), and the Department of Energy, BES-Chemical Sciences, Geosciences, and Biosciences Division under Grant no. DE-FG0203ER15457, the use of the Central Facilities supported by the MRSEC program of the National Science Foundation (DMR-0520513) at the Materials Research Center of Northwestern University and the West Light Foundation of the Chinese Academy of Sciences. JB and PSH thank the Welch Foundation and the NSF (DMR 0652150) for support. ",

year = "2008",

month = aug,

doi = "10.1016/j.jssc.2008.05.008",

language = "English (US)",

volume = "181",

pages = "2087--2091",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "8",

}

TY - JOUR

T1 - Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14

AU - Pan, Shilie

AU - Smit, Jared P.

AU - Marvel, Michael R.

AU - Stampler, Evan S.

AU - Haag, Jacob M.

AU - Baek, Jaewook

AU - Halasyamani, P. Shiv

AU - Poeppelmeier, Kenneth R.

N1 - Funding Information: The authors thank Charlotte L. Stern for assistance with crystallographic measurements. The authors gratefully acknowledge the financial support from the National Science Foundation (Solid State Chemistry Award nos. DMR-0312136 and DMR-0604454), and the Department of Energy, BES-Chemical Sciences, Geosciences, and Biosciences Division under Grant no. DE-FG0203ER15457, the use of the Central Facilities supported by the MRSEC program of the National Science Foundation (DMR-0520513) at the Materials Research Center of Northwestern University and the West Light Foundation of the Chinese Academy of Sciences. JB and PSH thank the Welch Foundation and the NSF (DMR 0652150) for support.

PY - 2008/8

Y1 - 2008/8

N2 - Bi2Cu5B4O14 crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a=10.1381(11) Å, b=9.3917(11) Å, c=3.4566(4) Å, α=105.570(2)°, β=92.275(2)°, γ=107.783(2)°, Z=1 and R1=0.0401 and wR2=0.0980. It is a layered structure that is built up from sheets of rectangular CuO4 and trigonal BO3 groups. The sheets are connected by infinite chains of edge shared BiO6 polyhedra that intersect the bc plane at an angle slightly greater than 90°. The second-harmonic generation efficiency of Bi2Cu5B4O14, using 1064 nm radiation, is about one half times that of KH2PO4.

AB - Bi2Cu5B4O14 crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a=10.1381(11) Å, b=9.3917(11) Å, c=3.4566(4) Å, α=105.570(2)°, β=92.275(2)°, γ=107.783(2)°, Z=1 and R1=0.0401 and wR2=0.0980. It is a layered structure that is built up from sheets of rectangular CuO4 and trigonal BO3 groups. The sheets are connected by infinite chains of edge shared BiO6 polyhedra that intersect the bc plane at an angle slightly greater than 90°. The second-harmonic generation efficiency of Bi2Cu5B4O14, using 1064 nm radiation, is about one half times that of KH2PO4.

KW - Crystal growth

KW - Crystal structure

KW - Nonlinear optical properties

KW - Oxide

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EP - 2091

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