Synthesis, crystal structure, and nonlinear optical properties of Li 6CuB4O10: A congruently melting compound with isolated [CuB4O10]6- units

Shilie Pan; Jared P. Smit; Byron Watkins; Michael R. Marvel; Charlotte L. Stern; Kenneth Poeppelmeier

doi:10.1021/ja0633114

Synthesis, crystal structure, and nonlinear optical properties of Li ₆CuB₄O₁₀: A congruently melting compound with isolated [CuB₄O₁₀]^6- units

Shilie Pan, Jared P. Smit, Byron Watkins, Michael R. Marvel, Charlotte L. Stern, Kenneth Poeppelmeier^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

216 Scopus citations

Abstract

Single crystals of Li₆CuB₄O₁₀ have been synthesized, and its crystal structure has been determined. Li ₆CuB₄O₁₀ crystallizes in the non-centrosymmetric triclinic space group P1 (No. 1). The structure consists of isolated [CuB₄O₁₀]^6- polyanions that are bridged by six LiO₄ tetrahedra. Li₆CuB₄O ₁₀ is a congruently melting compound. It produces SHG intensity similar to that produced by KH₂PO₄ and is phase-matchable.

Original language	English (US)
Pages (from-to)	11631-11634
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	128
Issue number	35
DOIs	https://doi.org/10.1021/ja0633114
State	Published - Sep 6 2006

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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@article{22f04f1c88c3432aa265e294e35f3506,

title = "Synthesis, crystal structure, and nonlinear optical properties of Li 6CuB4O10: A congruently melting compound with isolated [CuB4O10]6- units",

abstract = "Single crystals of Li6CuB4O10 have been synthesized, and its crystal structure has been determined. Li 6CuB4O10 crystallizes in the non-centrosymmetric triclinic space group P1 (No. 1). The structure consists of isolated [CuB4O10]6- polyanions that are bridged by six LiO4 tetrahedra. Li6CuB4O 10 is a congruently melting compound. It produces SHG intensity similar to that produced by KH2PO4 and is phase-matchable.",

author = "Shilie Pan and Smit, {Jared P.} and Byron Watkins and Marvel, {Michael R.} and Stern, {Charlotte L.} and Kenneth Poeppelmeier",

year = "2006",

month = sep,

day = "6",

doi = "10.1021/ja0633114",

language = "English (US)",

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journal = "Journal of the American Chemical Society",

issn = "0002-7863",

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TY - JOUR

T1 - Synthesis, crystal structure, and nonlinear optical properties of Li 6CuB4O10

T2 - A congruently melting compound with isolated [CuB4O10]6- units

AU - Pan, Shilie

AU - Smit, Jared P.

AU - Watkins, Byron

AU - Marvel, Michael R.

AU - Stern, Charlotte L.

AU - Poeppelmeier, Kenneth

PY - 2006/9/6

Y1 - 2006/9/6

N2 - Single crystals of Li6CuB4O10 have been synthesized, and its crystal structure has been determined. Li 6CuB4O10 crystallizes in the non-centrosymmetric triclinic space group P1 (No. 1). The structure consists of isolated [CuB4O10]6- polyanions that are bridged by six LiO4 tetrahedra. Li6CuB4O 10 is a congruently melting compound. It produces SHG intensity similar to that produced by KH2PO4 and is phase-matchable.

AB - Single crystals of Li6CuB4O10 have been synthesized, and its crystal structure has been determined. Li 6CuB4O10 crystallizes in the non-centrosymmetric triclinic space group P1 (No. 1). The structure consists of isolated [CuB4O10]6- polyanions that are bridged by six LiO4 tetrahedra. Li6CuB4O 10 is a congruently melting compound. It produces SHG intensity similar to that produced by KH2PO4 and is phase-matchable.

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ER -

Synthesis, crystal structure, and nonlinear optical properties of Li ₆CuB₄O₁₀: A congruently melting compound with isolated [CuB₄O₁₀]^6- units

Abstract

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