Synthesis of 1,2,3-triazoles by cycloadditions of azides with enol ethers

Dario R. Roque, Justin L. Neill, James W. Antoon, Erland P. Stevens*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

34 Scopus citations


1,2,3-Triazoles were prepared in good to modest yields by cycloaddition of alkyl azides onto enol ethers under solventless conditions. The reaction can access ring-fused triazoles that are unavailable by azide-alkyne cycloadditions and is easily scalable. The 1,2,3-triazole products bear functionality that may be readily derivatized.

Original languageEnglish (US)
Article numberM10204SS
Pages (from-to)2497-2502
Number of pages6
Issue number15
StatePublished - Oct 4 2005
Externally publishedYes


  • Azides
  • Cycloadditions
  • Heterocycles
  • Nitrogen
  • Regioselectivity

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry


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