Synthesis of catalytically active porous organic polymers from metalloporphyrin building blocks

Abraham M. Shultz; Omar K. Farha; Joseph T. Hupp; Son Binh T. Nguyen

doi:10.1039/c0sc00339e

Synthesis of catalytically active porous organic polymers from metalloporphyrin building blocks

Abraham M. Shultz, Omar K. Farha, Joseph T. Hupp, Son Binh T. Nguyen

Chemistry

Research output: Contribution to journal › Article › peer-review

171 Scopus citations

Abstract

The synthesis of a porous organic polymer (POP) containing free-base porphyrin subunits has been accomplished by the condensation of a bis(phthalic acid)porphyrin with tetra(4-aminophenyl)methane. Metallation by post-synthesis modification affords microporous materials incorporating either Fe or Mn(porphyrins) that have been shown to be active catalysts for both olefin epoxidation and alkane hydroxylation.

Original language	English (US)
Pages (from-to)	686-689
Number of pages	4
Journal	Chemical Science
Volume	2
Issue number	4
DOIs	https://doi.org/10.1039/c0sc00339e
State	Published - 2011

ASJC Scopus subject areas

General Chemistry

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abstract = "The synthesis of a porous organic polymer (POP) containing free-base porphyrin subunits has been accomplished by the condensation of a bis(phthalic acid)porphyrin with tetra(4-aminophenyl)methane. Metallation by post-synthesis modification affords microporous materials incorporating either Fe or Mn(porphyrins) that have been shown to be active catalysts for both olefin epoxidation and alkane hydroxylation.",

author = "Shultz, {Abraham M.} and Farha, {Omar K.} and Hupp, {Joseph T.} and Nguyen, {Son Binh T.}",

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journal = "Chemical Science",

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AU - Shultz, Abraham M.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

AU - Nguyen, Son Binh T.

PY - 2011

Y1 - 2011

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AB - The synthesis of a porous organic polymer (POP) containing free-base porphyrin subunits has been accomplished by the condensation of a bis(phthalic acid)porphyrin with tetra(4-aminophenyl)methane. Metallation by post-synthesis modification affords microporous materials incorporating either Fe or Mn(porphyrins) that have been shown to be active catalysts for both olefin epoxidation and alkane hydroxylation.

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Synthesis of catalytically active porous organic polymers from metalloporphyrin building blocks

Abstract

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