Synthesis of catalytically active porous organic polymers from metalloporphyrin building blocks

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Abstract

The synthesis of a porous organic polymer (POP) containing free-base porphyrin subunits has been accomplished by the condensation of a bis(phthalic acid)porphyrin with tetra(4-aminophenyl)methane. Metallation by post-synthesis modification affords microporous materials incorporating either Fe or Mn(porphyrins) that have been shown to be active catalysts for both olefin epoxidation and alkane hydroxylation.

Original languageEnglish (US)
Pages (from-to)686-689
Number of pages4
JournalChemical Science
Volume2
Issue number4
DOIs
StatePublished - May 9 2011

ASJC Scopus subject areas

  • Chemistry(all)

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