Synthesis of Diiminosuccinonitrile Complexes. Preparation and Structure of Bis(diiminosuccinonitrilo)platinum(II) trans-Dichlorobis(benzonitrile)platinum(II)

Joseph W. Lauher; James A Ibers

doi:10.1021/ic50145a040

Synthesis of Diiminosuccinonitrile Complexes. Preparation and Structure of Bis(diiminosuccinonitrilo)platinum(II) trans-Dichlorobis(benzonitrile)platinum(II)

Joseph W. Lauher, James A Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The complex bis(diiminosuccinonitrilo)platinum(II), [Pt(DISN)₂], and the analogs [Pd(DISN)₂] and [Ni(DISN)₂] have been prepared by the reaction in aqueous solution of the appropriate divalent metal halide with diaminomaleonitrile, oxygen, and a base. The reaction of diiminosuccinonitrile with bis(cyclooctadiene)nickel(0) also yields [Ni(DISN)₂]. [Pt(DISN)₂] can be prepared from PtCl₄, diaminomaleonitrile, and a base. An unusual material [Pt(DISN)₂] [PtCl₂(C₆H₅CN)₂] has been prepared by mixing stoichiometric quantities of the two components. The structure of this material has been determined from three-dimensional X-ray data collected by counter methods. The space group is C_2h ³-C2/m with a = 23.274 (6) Å,b = 12.439 (3) Å,c = 4.480 (2) Å, β = 98.68 (1)°, Z= 2, ρ_measd= 2.28 (1) g/cm³, and ρ_calcd= 2.278 g/cm³. The structure has been refined by full-matrix least-squares techniques to a conventional R index (on F) of 0.029 for the 734 reflections with F_o ²> 3σ(F₀ ²). The material consists of independent [Pt(DISN)₂] and [PtCl₂(C₆H₅CN)₂] molecules. The planar molecules form separate columns with interplanar distances of about 3.40 Å. The columns are held together by hydrogen bonds between the molecules. The bond distances found within the [Pt(DISN)₂] molecule suggest that the ligand has a delocalized electronic structure and that the compound is best described as a platinum(II) complex.

Original language	English (US)
Pages (from-to)	640-645
Number of pages	6
Journal	Inorganic Chemistry
Volume	14
Issue number	3
DOIs	https://doi.org/10.1021/ic50145a040
State	Published - Mar 1 1975

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic50145a040

Cite this

@article{bc7ba347cdbd4087b2406b315171c5b0,

title = "Synthesis of Diiminosuccinonitrile Complexes. Preparation and Structure of Bis(diiminosuccinonitrilo)platinum(II) trans-Dichlorobis(benzonitrile)platinum(II)",

abstract = "The complex bis(diiminosuccinonitrilo)platinum(II), [Pt(DISN)2], and the analogs [Pd(DISN)2] and [Ni(DISN)2] have been prepared by the reaction in aqueous solution of the appropriate divalent metal halide with diaminomaleonitrile, oxygen, and a base. The reaction of diiminosuccinonitrile with bis(cyclooctadiene)nickel(0) also yields [Ni(DISN)2]. [Pt(DISN)2] can be prepared from PtCl4, diaminomaleonitrile, and a base. An unusual material [Pt(DISN)2] [PtCl2(C6H5CN)2] has been prepared by mixing stoichiometric quantities of the two components. The structure of this material has been determined from three-dimensional X-ray data collected by counter methods. The space group is C2h 3-C2/m with a = 23.274 (6) {\AA},b = 12.439 (3) {\AA},c = 4.480 (2) {\AA}, β = 98.68 (1)°, Z= 2, ρmeasd= 2.28 (1) g/cm3, and ρcalcd= 2.278 g/cm3. The structure has been refined by full-matrix least-squares techniques to a conventional R index (on F) of 0.029 for the 734 reflections with Fo 2> 3σ(F0 2). The material consists of independent [Pt(DISN)2] and [PtCl2(C6H5CN)2] molecules. The planar molecules form separate columns with interplanar distances of about 3.40 {\AA}. The columns are held together by hydrogen bonds between the molecules. The bond distances found within the [Pt(DISN)2] molecule suggest that the ligand has a delocalized electronic structure and that the compound is best described as a platinum(II) complex.",

author = "Lauher, {Joseph W.} and Ibers, {James A}",

year = "1975",

month = mar,

day = "1",

doi = "10.1021/ic50145a040",

language = "English (US)",

volume = "14",

pages = "640--645",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - Synthesis of Diiminosuccinonitrile Complexes. Preparation and Structure of Bis(diiminosuccinonitrilo)platinum(II) trans-Dichlorobis(benzonitrile)platinum(II)

AU - Lauher, Joseph W.

AU - Ibers, James A

PY - 1975/3/1

Y1 - 1975/3/1

N2 - The complex bis(diiminosuccinonitrilo)platinum(II), [Pt(DISN)2], and the analogs [Pd(DISN)2] and [Ni(DISN)2] have been prepared by the reaction in aqueous solution of the appropriate divalent metal halide with diaminomaleonitrile, oxygen, and a base. The reaction of diiminosuccinonitrile with bis(cyclooctadiene)nickel(0) also yields [Ni(DISN)2]. [Pt(DISN)2] can be prepared from PtCl4, diaminomaleonitrile, and a base. An unusual material [Pt(DISN)2] [PtCl2(C6H5CN)2] has been prepared by mixing stoichiometric quantities of the two components. The structure of this material has been determined from three-dimensional X-ray data collected by counter methods. The space group is C2h 3-C2/m with a = 23.274 (6) Å,b = 12.439 (3) Å,c = 4.480 (2) Å, β = 98.68 (1)°, Z= 2, ρmeasd= 2.28 (1) g/cm3, and ρcalcd= 2.278 g/cm3. The structure has been refined by full-matrix least-squares techniques to a conventional R index (on F) of 0.029 for the 734 reflections with Fo 2> 3σ(F0 2). The material consists of independent [Pt(DISN)2] and [PtCl2(C6H5CN)2] molecules. The planar molecules form separate columns with interplanar distances of about 3.40 Å. The columns are held together by hydrogen bonds between the molecules. The bond distances found within the [Pt(DISN)2] molecule suggest that the ligand has a delocalized electronic structure and that the compound is best described as a platinum(II) complex.

AB - The complex bis(diiminosuccinonitrilo)platinum(II), [Pt(DISN)2], and the analogs [Pd(DISN)2] and [Ni(DISN)2] have been prepared by the reaction in aqueous solution of the appropriate divalent metal halide with diaminomaleonitrile, oxygen, and a base. The reaction of diiminosuccinonitrile with bis(cyclooctadiene)nickel(0) also yields [Ni(DISN)2]. [Pt(DISN)2] can be prepared from PtCl4, diaminomaleonitrile, and a base. An unusual material [Pt(DISN)2] [PtCl2(C6H5CN)2] has been prepared by mixing stoichiometric quantities of the two components. The structure of this material has been determined from three-dimensional X-ray data collected by counter methods. The space group is C2h 3-C2/m with a = 23.274 (6) Å,b = 12.439 (3) Å,c = 4.480 (2) Å, β = 98.68 (1)°, Z= 2, ρmeasd= 2.28 (1) g/cm3, and ρcalcd= 2.278 g/cm3. The structure has been refined by full-matrix least-squares techniques to a conventional R index (on F) of 0.029 for the 734 reflections with Fo 2> 3σ(F0 2). The material consists of independent [Pt(DISN)2] and [PtCl2(C6H5CN)2] molecules. The planar molecules form separate columns with interplanar distances of about 3.40 Å. The columns are held together by hydrogen bonds between the molecules. The bond distances found within the [Pt(DISN)2] molecule suggest that the ligand has a delocalized electronic structure and that the compound is best described as a platinum(II) complex.

UR - http://www.scopus.com/inward/record.url?scp=33847801705&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33847801705&partnerID=8YFLogxK

U2 - 10.1021/ic50145a040

DO - 10.1021/ic50145a040

M3 - Article

AN - SCOPUS:33847801705

SN - 0020-1669

VL - 14

SP - 640

EP - 645

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3

ER -

Synthesis of Diiminosuccinonitrile Complexes. Preparation and Structure of Bis(diiminosuccinonitrilo)platinum(II) trans-Dichlorobis(benzonitrile)platinum(II)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this