Synthesis of lithium chromium oxide from a hydroxide precursor

J. L. Allen, Kenneth Poeppelmeier*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

The room temperature reaction of Cr(OH)3·3H2O with LiOH·H2O results in an X-ray amorphous solid that appears to form through condensation of the hydrogen-bonded Cr(OH)3·3H2O octahedra into edge and corner sharing octahedra. The reaction is explained in terms of analogous sol-gel chemistry of chromium(III). The X-ray amorphous product can be decomposed to yield LiCrO2 with surface area higher than conventional syntheses.

Original languageEnglish (US)
Pages (from-to)1301-1310
Number of pages10
JournalPolyhedron
Volume13
Issue number8
DOIs
StatePublished - Jan 1 1994

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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