Synthesis of monodisperse CeO2–ZrO2 particles exhibiting cyclic superelasticity over hundreds of cycles

Zehui Du, Pengcheng Ye, Xiao Mei Zeng, Christopher A. Schuh, Nobumichi Tamura, Xinran Zhou, Chee Lip Gan*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

19 Scopus citations


Nano- and microscale CeO2–ZrO2 (CZ) shape memory ceramics are promising materials for smart micro-electro-mechanical systems (MEMS), sensing, actuation and energy damping applications, but the processing science for scalable production of such small volume ceramics has not yet been established. Herein, we report a modified sol-gel method to synthesize highly monodisperse spherical CZ particles with diameters in the range of ~0.8-3.0 μm. Synchrotron X-ray micro-diffraction (μSXRD) confirmed that most of the particles are single crystal after annealing at 1450°C. Having a monocrystalline structure and a small specimen length scale, the particles exhibit significantly enhanced shape memory and superelasticity properties with up to ~4.7% compression being completely recoverable. Highly reproducible superelasticity through over five hundred strain cycles, with dissipated energy up to ~40 MJ/m3 per cycle, is achieved in the CZ particles containing 16 mol% ceria. This cycling capability is enhanced by ten times compared with our first demonstration using micropillars (only 50 cycles in Lai et al, Science, 2013, 341, 1505). Furthermore, the effects of cycling and testing temperature (in 25°C-400°C) on superelasticity have been investigated.

Original languageEnglish (US)
Pages (from-to)4199-4208
Number of pages10
JournalJournal of the American Ceramic Society
Issue number9
StatePublished - Sep 2017


  • CeO–ZrO
  • particles
  • shape memory
  • sol-gel
  • superelasticity

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry


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