Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net: Significant enhancement in the degradation of a nerve agent simulant

Peng Li; Rachel C. Klet; Su Young Moon; Timothy C. Wang; Pravas Deria; Aaron W. Peters; Benjamin M. Klahr; Hea Jung Park; Salih S. Al-Juaid; Joseph T Hupp; Omar k Farha

doi:10.1039/c5cc03398e

Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net: Significant enhancement in the degradation of a nerve agent simulant

Peng Li, Rachel C. Klet, Su Young Moon, Timothy C. Wang, Pravas Deria, Aaron W. Peters, Benjamin M. Klahr, Hea Jung Park, Salih S. Al-Juaid, Joseph T Hupp^*, Omar k Farha

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

210 Scopus citations

Abstract

The synthesis of nano-sized particles of NU-1000 (length from 75 nm to 1200 nm) and PCN-222/MOF-545 (length from 350 nm to 900 nm) is reported. The catalytic hydrolysis of methyl paraoxon was investigated as a function of NU-1000 crystallite size and a significant enhancement in the rate was observed for the nano-sized crystals compared to microcrystals.

Original language	English (US)
Pages (from-to)	10925-10928
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	54
DOIs	https://doi.org/10.1039/c5cc03398e
State	Published - Jul 11 2015

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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Li, P., Klet, R. C., Moon, S. Y., Wang, T. C., Deria, P., Peters, A. W., Klahr, B. M., Park, H. J., Al-Juaid, S. S., Hupp, J. T., & Farha, O. K. (2015). Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net: Significant enhancement in the degradation of a nerve agent simulant. Chemical Communications, 51(54), 10925-10928. https://doi.org/10.1039/c5cc03398e

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title = "Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net: Significant enhancement in the degradation of a nerve agent simulant",

abstract = "The synthesis of nano-sized particles of NU-1000 (length from 75 nm to 1200 nm) and PCN-222/MOF-545 (length from 350 nm to 900 nm) is reported. The catalytic hydrolysis of methyl paraoxon was investigated as a function of NU-1000 crystallite size and a significant enhancement in the rate was observed for the nano-sized crystals compared to microcrystals.",

author = "Peng Li and Klet, {Rachel C.} and Moon, {Su Young} and Wang, {Timothy C.} and Pravas Deria and Peters, {Aaron W.} and Klahr, {Benjamin M.} and Park, {Hea Jung} and Al-Juaid, {Salih S.} and Hupp, {Joseph T} and Farha, {Omar k}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = jul,

day = "11",

doi = "10.1039/c5cc03398e",

language = "English (US)",

volume = "51",

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T1 - Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net

T2 - Significant enhancement in the degradation of a nerve agent simulant

AU - Li, Peng

AU - Klet, Rachel C.

AU - Moon, Su Young

AU - Wang, Timothy C.

AU - Deria, Pravas

AU - Peters, Aaron W.

AU - Klahr, Benjamin M.

AU - Park, Hea Jung

AU - Al-Juaid, Salih S.

AU - Hupp, Joseph T

AU - Farha, Omar k

PY - 2015/7/11

Y1 - 2015/7/11

N2 - The synthesis of nano-sized particles of NU-1000 (length from 75 nm to 1200 nm) and PCN-222/MOF-545 (length from 350 nm to 900 nm) is reported. The catalytic hydrolysis of methyl paraoxon was investigated as a function of NU-1000 crystallite size and a significant enhancement in the rate was observed for the nano-sized crystals compared to microcrystals.

AB - The synthesis of nano-sized particles of NU-1000 (length from 75 nm to 1200 nm) and PCN-222/MOF-545 (length from 350 nm to 900 nm) is reported. The catalytic hydrolysis of methyl paraoxon was investigated as a function of NU-1000 crystallite size and a significant enhancement in the rate was observed for the nano-sized crystals compared to microcrystals.

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DO - 10.1039/c5cc03398e

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SN - 1359-7345

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SP - 10925

EP - 10928

JO - Chemical Communications

JF - Chemical Communications

IS - 54

ER -

Synthesis of nanocrystals of Zr-based metal-organic frameworks with csq-net: Significant enhancement in the degradation of a nerve agent simulant

Abstract

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