Synthesis of New Five-Atom-Linked Capped Porphyrins

Wuping Ma; Carla Slebodnick; James A. Ibers

doi:10.1021/jo00075a031

Synthesis of New Five-Atom-Linked Capped Porphyrins

Wuping Ma, Carla Slebodnick, James A. Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The synthesis and characterization of three new five-atom-linked “capped” porphyrins, 6, 12, and 18, are reported. The general synthetic procedure involves synthesis of a tetraaldehyde “cap” by reacting the five-atom “arm” with 1,2,4,5-tetrahydroxybenzene in DMSO solvent in the presence of KOH. The tetraaldehyde and pyrrole are reacted to form the capped porphyrin. These compounds are useful as models for the active sites of heme proteins.

Original language	English (US)
Pages (from-to)	6349-6353
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	58
Issue number	23
DOIs	https://doi.org/10.1021/jo00075a031
State	Published - Jan 1 1993

ASJC Scopus subject areas

Organic Chemistry

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title = "Synthesis of New Five-Atom-Linked Capped Porphyrins",

abstract = "The synthesis and characterization of three new five-atom-linked “capped” porphyrins, 6, 12, and 18, are reported. The general synthetic procedure involves synthesis of a tetraaldehyde “cap” by reacting the five-atom “arm” with 1,2,4,5-tetrahydroxybenzene in DMSO solvent in the presence of KOH. The tetraaldehyde and pyrrole are reacted to form the capped porphyrin. These compounds are useful as models for the active sites of heme proteins.",

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year = "1993",

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AU - Ibers, James A.

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N2 - The synthesis and characterization of three new five-atom-linked “capped” porphyrins, 6, 12, and 18, are reported. The general synthetic procedure involves synthesis of a tetraaldehyde “cap” by reacting the five-atom “arm” with 1,2,4,5-tetrahydroxybenzene in DMSO solvent in the presence of KOH. The tetraaldehyde and pyrrole are reacted to form the capped porphyrin. These compounds are useful as models for the active sites of heme proteins.

AB - The synthesis and characterization of three new five-atom-linked “capped” porphyrins, 6, 12, and 18, are reported. The general synthetic procedure involves synthesis of a tetraaldehyde “cap” by reacting the five-atom “arm” with 1,2,4,5-tetrahydroxybenzene in DMSO solvent in the presence of KOH. The tetraaldehyde and pyrrole are reacted to form the capped porphyrin. These compounds are useful as models for the active sites of heme proteins.

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Synthesis of New Five-Atom-Linked Capped Porphyrins

Abstract

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