Synthesis of the one-dimensional compound (Ph4P)[In(P2Se6)] in a Ph4P+-containing selenophosphate flux, and structure of [In(P2Se6)2]5--a discrete molecular fragment of the [In(P2se6)]nn- chain

Konstantinos Chondroudis; Debojit Chakrabarty; Enos A. Axtell; Mercouri G. Kanatzidis

doi:10.1002/(sici)1521-3749(199806)624:6<975::aid-zaac975>3.0.co;2-1

Synthesis of the one-dimensional compound (Ph₄P)[In(P₂Se₆)] in a Ph₄P⁺-containing selenophosphate flux, and structure of [In(P₂Se₆)₂]^5--a discrete molecular fragment of the [In(P₂se₆)]_n^n- chain

Konstantinos Chondroudis, Debojit Chakrabarty, Enos A. Axtell, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The reaction of one equivalent of In with a molten flux of (Ph₄P)₂Se₅ and P₂Se₅ (1:2), at 250°C gave the (Ph₄P)[In(P₂Se₆)] (I). Stoichiometric elemental synthesis at 750°C produced the Cs₅In(P₂Se₆)₂ (II). The thin, yellow crystals of (I), and the irregular, dark orange crystals of (II), appear to be air-and water-stable. Compound (I) crystallizes in the monoclinic space group C2/c (no. 15) and at 23°C: a = 23.127(7) Å, b = 6.564(1) Å, c = 19.083(3) Å, β = 97.42(2)°, V = 2873(1) Å³, Z = 4, final R/R_w = 4.4/5.2%. Compound (II) crystallizes in the tetragonal space group P4₂/m (no. 84) and at 23°C: a = b = 13.886(1) Å, c = 7.597(2) Å, V = 1464.9(3) Å³, Z = 2, final R/R_w = 3.9/ 5.1%. Compound (I) contains infinite [In(P₂Se₆)]_n^n- with a structure related to that of K₂FeP₂Se₆. Compound (II) contains the discrete [In(P₂Se₆)₂]^5- which can be viewed as a fragment of the [In(P₂Se₆)]_n^n- chain.

Original language	English (US)
Pages (from-to)	975-979
Number of pages	5
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	624
Issue number	6
DOIs	https://doi.org/10.1002/(sici)1521-3749(199806)624:6<975::aid-zaac975>3.0.co;2-1
State	Published - 1998

Keywords

Indium
Selenophosphates
Tetraphenylphosphonium compounds

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/(sici)1521-3749(199806)624:6<975::aid-zaac975>3.0.co;2-1

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Chondroudis, K., Chakrabarty, D., Axtell, E. A., & Kanatzidis, M. G. (1998). Synthesis of the one-dimensional compound (Ph₄P)[In(P₂Se₆)] in a Ph₄P⁺-containing selenophosphate flux, and structure of [In(P₂Se₆)₂]^5--a discrete molecular fragment of the [In(P₂se₆)]_n^n- chain. Zeitschrift fur Anorganische und Allgemeine Chemie, 624(6), 975-979. https://doi.org/10.1002/(sici)1521-3749(199806)624:6<975::aid-zaac975>3.0.co;2-1

@article{1a0e66f5a84b40d58ce3ff76d6e21088,

title = "Synthesis of the one-dimensional compound (Ph4P)[In(P2Se6)] in a Ph4P+-containing selenophosphate flux, and structure of [In(P2Se6)2]5--a discrete molecular fragment of the [In(P2se6)]nn- chain",

abstract = "The reaction of one equivalent of In with a molten flux of (Ph4P)2Se5 and P2Se5 (1:2), at 250°C gave the (Ph4P)[In(P2Se6)] (I). Stoichiometric elemental synthesis at 750°C produced the Cs5In(P2Se6)2 (II). The thin, yellow crystals of (I), and the irregular, dark orange crystals of (II), appear to be air-and water-stable. Compound (I) crystallizes in the monoclinic space group C2/c (no. 15) and at 23°C: a = 23.127(7) {\AA}, b = 6.564(1) {\AA}, c = 19.083(3) {\AA}, β = 97.42(2)°, V = 2873(1) {\AA}3, Z = 4, final R/Rw = 4.4/5.2%. Compound (II) crystallizes in the tetragonal space group P42/m (no. 84) and at 23°C: a = b = 13.886(1) {\AA}, c = 7.597(2) {\AA}, V = 1464.9(3) {\AA}3, Z = 2, final R/Rw = 3.9/ 5.1%. Compound (I) contains infinite [In(P2Se6)]nn- with a structure related to that of K2FeP2Se6. Compound (II) contains the discrete [In(P2Se6)2]5- which can be viewed as a fragment of the [In(P2Se6)]nn- chain.",

keywords = "Indium, Selenophosphates, Tetraphenylphosphonium compounds",

author = "Konstantinos Chondroudis and Debojit Chakrabarty and Axtell, {Enos A.} and Kanatzidis, {Mercouri G.}",

year = "1998",

doi = "10.1002/(sici)1521-3749(199806)624:6<975::aid-zaac975>3.0.co;2-1",

language = "English (US)",

volume = "624",

pages = "975--979",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "6",

}

Chondroudis, K, Chakrabarty, D, Axtell, EA & Kanatzidis, MG 1998, 'Synthesis of the one-dimensional compound (Ph₄P)[In(P₂Se₆)] in a Ph₄P⁺-containing selenophosphate flux, and structure of [In(P₂Se₆)₂]^5--a discrete molecular fragment of the [In(P₂se₆)]_n^n- chain', Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 624, no. 6, pp. 975-979. https://doi.org/10.1002/(sici)1521-3749(199806)624:6<975::aid-zaac975>3.0.co;2-1

Synthesis of the one-dimensional compound (Ph₄P)[In(P₂Se₆)] in a Ph₄P⁺-containing selenophosphate flux, and structure of [In(P₂Se₆)₂]^5--a discrete molecular fragment of the [In(P₂se₆)]_n^n- chain. / Chondroudis, Konstantinos; Chakrabarty, Debojit; Axtell, Enos A. et al.
In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 624, No. 6, 1998, p. 975-979.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of the one-dimensional compound (Ph4P)[In(P2Se6)] in a Ph4P+-containing selenophosphate flux, and structure of [In(P2Se6)2]5--a discrete molecular fragment of the [In(P2se6)]nn- chain

AU - Chondroudis, Konstantinos

AU - Chakrabarty, Debojit

AU - Axtell, Enos A.

AU - Kanatzidis, Mercouri G.

PY - 1998

Y1 - 1998

N2 - The reaction of one equivalent of In with a molten flux of (Ph4P)2Se5 and P2Se5 (1:2), at 250°C gave the (Ph4P)[In(P2Se6)] (I). Stoichiometric elemental synthesis at 750°C produced the Cs5In(P2Se6)2 (II). The thin, yellow crystals of (I), and the irregular, dark orange crystals of (II), appear to be air-and water-stable. Compound (I) crystallizes in the monoclinic space group C2/c (no. 15) and at 23°C: a = 23.127(7) Å, b = 6.564(1) Å, c = 19.083(3) Å, β = 97.42(2)°, V = 2873(1) Å3, Z = 4, final R/Rw = 4.4/5.2%. Compound (II) crystallizes in the tetragonal space group P42/m (no. 84) and at 23°C: a = b = 13.886(1) Å, c = 7.597(2) Å, V = 1464.9(3) Å3, Z = 2, final R/Rw = 3.9/ 5.1%. Compound (I) contains infinite [In(P2Se6)]nn- with a structure related to that of K2FeP2Se6. Compound (II) contains the discrete [In(P2Se6)2]5- which can be viewed as a fragment of the [In(P2Se6)]nn- chain.

AB - The reaction of one equivalent of In with a molten flux of (Ph4P)2Se5 and P2Se5 (1:2), at 250°C gave the (Ph4P)[In(P2Se6)] (I). Stoichiometric elemental synthesis at 750°C produced the Cs5In(P2Se6)2 (II). The thin, yellow crystals of (I), and the irregular, dark orange crystals of (II), appear to be air-and water-stable. Compound (I) crystallizes in the monoclinic space group C2/c (no. 15) and at 23°C: a = 23.127(7) Å, b = 6.564(1) Å, c = 19.083(3) Å, β = 97.42(2)°, V = 2873(1) Å3, Z = 4, final R/Rw = 4.4/5.2%. Compound (II) crystallizes in the tetragonal space group P42/m (no. 84) and at 23°C: a = b = 13.886(1) Å, c = 7.597(2) Å, V = 1464.9(3) Å3, Z = 2, final R/Rw = 3.9/ 5.1%. Compound (I) contains infinite [In(P2Se6)]nn- with a structure related to that of K2FeP2Se6. Compound (II) contains the discrete [In(P2Se6)2]5- which can be viewed as a fragment of the [In(P2Se6)]nn- chain.

KW - Indium

KW - Selenophosphates

KW - Tetraphenylphosphonium compounds

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M3 - Article

AN - SCOPUS:0032360789

SN - 0044-2313

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SP - 975

EP - 979

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 6

ER -

Chondroudis K, Chakrabarty D, Axtell EA, Kanatzidis MG. Synthesis of the one-dimensional compound (Ph₄P)[In(P₂Se₆)] in a Ph₄P⁺-containing selenophosphate flux, and structure of [In(P₂Se₆)₂]^5--a discrete molecular fragment of the [In(P₂se₆)]_n^n- chain. Zeitschrift fur Anorganische und Allgemeine Chemie. 1998;624(6):975-979. doi: 10.1002/(sici)1521-3749(199806)624:6<975::aid-zaac975>3.0.co;2-1