Synthesis, structure, and properties of Li2Pb 2CuB4O10 with isolated [CuB4O 10]6- units

Hongyi Li; Shilie Pan; Hongping Wu; Jared P. Smit; Kenneth R. Poeppelmeier

doi:10.1016/j.jallcom.2010.11.206

Synthesis, structure, and properties of Li₂Pb ₂CuB₄O₁₀ with isolated [CuB₄O ₁₀]^6- units

Hongyi Li, Shilie Pan^*, Hongping Wu, Jared P. Smit, Kenneth R. Poeppelmeier

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The copper borate Li₂Pb₂CuB₄O₁₀ has been synthesized in air by the standard solid-state reaction at temperature in the range 550-650 °C and the structure of Li₂Pb ₂CuB₄O₁₀ was determined by single-crystal X-ray diffraction. Li₂Pb₂CuB₄O₁₀ crystallizes in the monoclinic space group C2/c (no. 15) with a = 16.8419(12), b = 4.7895(4), c = 13.8976(10) , and β = 125.3620(10)°, V = 914.22(12) ³, and Z = 4, as determined by single-crystal X-ray diffraction. The Li₂Pb₂CuB₄O₁₀ structure exhibits isolated units of stoichiometry [CuB₄O₁₀]^6- that are built from CuO₄ distorted square planes and triangular BO₃ groups. The IR spectroscopy and thermal analysis investigations of Li₂Pb₂CuB₄O₁₀ are also presented.

Original language	English (US)
Pages (from-to)	3310-3313
Number of pages	4
Journal	Journal of Alloys and Compounds
Volume	509
Issue number	7
DOIs	https://doi.org/10.1016/j.jallcom.2010.11.206
State	Published - Feb 17 2011

Keywords

Crystal structure
Oxide materials
Solid state reactions
X-ray diffraction

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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@article{2b3a82c587df44d8a5ed39b1d1a5b7fb,

title = "Synthesis, structure, and properties of Li2Pb 2CuB4O10 with isolated [CuB4O 10]6- units",

abstract = "The copper borate Li2Pb2CuB4O10 has been synthesized in air by the standard solid-state reaction at temperature in the range 550-650 °C and the structure of Li2Pb 2CuB4O10 was determined by single-crystal X-ray diffraction. Li2Pb2CuB4O10 crystallizes in the monoclinic space group C2/c (no. 15) with a = 16.8419(12), b = 4.7895(4), c = 13.8976(10) , and β = 125.3620(10)°, V = 914.22(12) 3, and Z = 4, as determined by single-crystal X-ray diffraction. The Li2Pb2CuB4O10 structure exhibits isolated units of stoichiometry [CuB4O10]6- that are built from CuO4 distorted square planes and triangular BO3 groups. The IR spectroscopy and thermal analysis investigations of Li2Pb2CuB4O10 are also presented.",

keywords = "Crystal structure, Oxide materials, Solid state reactions, X-ray diffraction",

author = "Hongyi Li and Shilie Pan and Hongping Wu and Smit, {Jared P.} and Poeppelmeier, {Kenneth R.}",

note = "Funding Information: We gratefully acknowledge the support from the “ National Natural Science Foundation of China ” (Grant No. 50802110 ), the “One Hundred Talents Project Foundation Program” of Chinese Academy of Sciences, the “Western Light Joint Scholar Foundation” Program of Chinese Academy of Sciences, the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (Grant No. 20091001 ), the Natural Science Foundation of Xinjiang Uygur Autonomous Region of China (Grant Nos. 200821159, 2009211B33 ) and the “High Technology Research and Development Program” of Xinjiang Uygur Autonomous Region of China (Grant No. 200816120 ). KRP acknowledges the National Science Foundation Solid State Chemistry Award No. DMR-0604454. ",

year = "2011",

month = feb,

day = "17",

doi = "10.1016/j.jallcom.2010.11.206",

language = "English (US)",

volume = "509",

pages = "3310--3313",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier BV",

number = "7",

}

TY - JOUR

T1 - Synthesis, structure, and properties of Li2Pb 2CuB4O10 with isolated [CuB4O 10]6- units

AU - Li, Hongyi

AU - Pan, Shilie

AU - Wu, Hongping

AU - Smit, Jared P.

AU - Poeppelmeier, Kenneth R.

N1 - Funding Information: We gratefully acknowledge the support from the “ National Natural Science Foundation of China ” (Grant No. 50802110 ), the “One Hundred Talents Project Foundation Program” of Chinese Academy of Sciences, the “Western Light Joint Scholar Foundation” Program of Chinese Academy of Sciences, the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (Grant No. 20091001 ), the Natural Science Foundation of Xinjiang Uygur Autonomous Region of China (Grant Nos. 200821159, 2009211B33 ) and the “High Technology Research and Development Program” of Xinjiang Uygur Autonomous Region of China (Grant No. 200816120 ). KRP acknowledges the National Science Foundation Solid State Chemistry Award No. DMR-0604454.

PY - 2011/2/17

Y1 - 2011/2/17

N2 - The copper borate Li2Pb2CuB4O10 has been synthesized in air by the standard solid-state reaction at temperature in the range 550-650 °C and the structure of Li2Pb 2CuB4O10 was determined by single-crystal X-ray diffraction. Li2Pb2CuB4O10 crystallizes in the monoclinic space group C2/c (no. 15) with a = 16.8419(12), b = 4.7895(4), c = 13.8976(10) , and β = 125.3620(10)°, V = 914.22(12) 3, and Z = 4, as determined by single-crystal X-ray diffraction. The Li2Pb2CuB4O10 structure exhibits isolated units of stoichiometry [CuB4O10]6- that are built from CuO4 distorted square planes and triangular BO3 groups. The IR spectroscopy and thermal analysis investigations of Li2Pb2CuB4O10 are also presented.

AB - The copper borate Li2Pb2CuB4O10 has been synthesized in air by the standard solid-state reaction at temperature in the range 550-650 °C and the structure of Li2Pb 2CuB4O10 was determined by single-crystal X-ray diffraction. Li2Pb2CuB4O10 crystallizes in the monoclinic space group C2/c (no. 15) with a = 16.8419(12), b = 4.7895(4), c = 13.8976(10) , and β = 125.3620(10)°, V = 914.22(12) 3, and Z = 4, as determined by single-crystal X-ray diffraction. The Li2Pb2CuB4O10 structure exhibits isolated units of stoichiometry [CuB4O10]6- that are built from CuO4 distorted square planes and triangular BO3 groups. The IR spectroscopy and thermal analysis investigations of Li2Pb2CuB4O10 are also presented.

KW - Crystal structure

KW - Oxide materials

KW - Solid state reactions

KW - X-ray diffraction

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U2 - 10.1016/j.jallcom.2010.11.206

DO - 10.1016/j.jallcom.2010.11.206

M3 - Article

AN - SCOPUS:78751614249

VL - 509

SP - 3310

EP - 3313

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

IS - 7

ER -