Tandem In2O3-Pt/Al2O3catalyst for coupling of propane dehydrogenation to selective H2combustion

Huan Yan, Kun He, Izabela A. Samek, Dian Jing, MacY G. Nanda, Peter C. Stair*, Justin M. Notestein

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

Tandem catalysis couples multiple reactions and promises to improve chemical processing, but precise spatiotemporal control over reactive intermediates remains elusive. We used atomic layer deposition to grow In2O3over Pt/Al2O3, and this nanostructure kinetically couples the domains through surface hydrogen atom transfer, resulting in propane dehydrogenation (PDH) to propylene by platinum, then selective hydrogen combustion by In2O3, without excessive hydrocarbon combustion. Other nanostructures, including platinum on In2O3or platinum mixed with In2O3, favor propane combustion because they cannot organize the reactions sequentially. The net effect is rapid and stable oxidative dehydrogenation of propane at high per-pass yields exceeding the PDH equilibrium. Tandem catalysis using this nanoscale overcoating geometry is validated as an opportunity for highly selective catalytic performance in a grand challenge reaction.

Original languageEnglish (US)
Pages (from-to)1257-1260
Number of pages4
JournalScience
Volume371
Issue number6535
DOIs
StatePublished - Mar 19 2021

ASJC Scopus subject areas

  • General

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