Technetium dichloride: A new binary halide containing metal-metal multiple bonds

Frederic Poineau*, Christos D. Malliakas, Philippe F. Weck, Brian L. Scott, Erik V. Johnstone, Paul M. Forster, Eunja Kim, Mercouri G. Kanatzidis, Kenneth R. Czerwinski, Alfred P. Sattelberger

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

27 Scopus citations

Abstract

Technetium dichloride has been discovered. It was synthesized from the elements and characterized by several physical techniques, including single crystal X-ray diffraction. In the solid state, technetium dichloride exhibits a new structure type consisting of infinite chains of face sharing [Tc 2Cl8] rectangular prisms that are packed in a commensurate supercell. The metal-metal separation in the prisms is 2.127(2) Å, a distance consistent with the presence of a Tc=Tc triple bond that is also supported by electronic structure calculations.

Original languageEnglish (US)
Pages (from-to)8814-8817
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number23
DOIs
StatePublished - Jun 15 2011

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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