Terthienyl-based redox-switchable hemilabile ligands: Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments?

Dana A. Weinberger; Thomas B. Higgins; Chad A. Mirkin; Louise M. Liable-Sands; Arnold L. Rheingold

doi:10.1002/(SICI)1521-3773(19990903)38:17<2565::AID-ANIE2565>3.0.CO;2-U

Terthienyl-based redox-switchable hemilabile ligands: Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments?

Dana A. Weinberger, Thomas B. Higgins, Chad A. Mirkin^*, Louise M. Liable-Sands, Arnold L. Rheingold

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

By controlling the extent of oxidation of the polymeric forms of the new class of isolable, polymerizable terthienyl Ru(II) complexes 1, one can modulate both the binding strength of the polymer backbone for Ru(II) and the electronic nature of the bound metal centers.

Original language	English (US)
Pages (from-to)	2565-2568
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	17
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990903)38:17<2565::AID-ANIE2565>3.0.CO;2-U
State	Published - Sep 3 1999

Keywords

Conducting materials
P ligands
Polymers
Redox chemistry
Ruthenium

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/(SICI)1521-3773(19990903)38:17<2565::AID-ANIE2565>3.0.CO;2-U

Cite this

Weinberger, D. A., Higgins, T. B., Mirkin, C. A., Liable-Sands, L. M., & Rheingold, A. L. (1999). Terthienyl-based redox-switchable hemilabile ligands: Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments? Angewandte Chemie - International Edition, 38(17), 2565-2568. https://doi.org/10.1002/(SICI)1521-3773(19990903)38:17<2565::AID-ANIE2565>3.0.CO;2-U

@article{4bf797eb663a487d85bc7b2993df365b,

title = "Terthienyl-based redox-switchable hemilabile ligands: Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments?",

abstract = "By controlling the extent of oxidation of the polymeric forms of the new class of isolable, polymerizable terthienyl Ru(II) complexes 1, one can modulate both the binding strength of the polymer backbone for Ru(II) and the electronic nature of the bound metal centers.",

keywords = "Conducting materials, P ligands, Polymers, Redox chemistry, Ruthenium",

author = "Weinberger, {Dana A.} and Higgins, {Thomas B.} and Mirkin, {Chad A.} and Liable-Sands, {Louise M.} and Rheingold, {Arnold L.}",

year = "1999",

month = sep,

day = "3",

doi = "10.1002/(SICI)1521-3773(19990903)38:17<2565::AID-ANIE2565>3.0.CO;2-U",

language = "English (US)",

volume = "38",

pages = "2565--2568",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "17",

}

Weinberger, DA, Higgins, TB, Mirkin, CA, Liable-Sands, LM & Rheingold, AL 1999, 'Terthienyl-based redox-switchable hemilabile ligands: Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments?', Angewandte Chemie - International Edition, vol. 38, no. 17, pp. 2565-2568. https://doi.org/10.1002/(SICI)1521-3773(19990903)38:17<2565::AID-ANIE2565>3.0.CO;2-U

Terthienyl-based redox-switchable hemilabile ligands: Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments? / Weinberger, Dana A.; Higgins, Thomas B.; Mirkin, Chad A. et al.
In: Angewandte Chemie - International Edition, Vol. 38, No. 17, 03.09.1999, p. 2565-2568.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Terthienyl-based redox-switchable hemilabile ligands

T2 - Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments?

AU - Weinberger, Dana A.

AU - Higgins, Thomas B.

AU - Mirkin, Chad A.

AU - Liable-Sands, Louise M.

AU - Rheingold, Arnold L.

PY - 1999/9/3

Y1 - 1999/9/3

N2 - By controlling the extent of oxidation of the polymeric forms of the new class of isolable, polymerizable terthienyl Ru(II) complexes 1, one can modulate both the binding strength of the polymer backbone for Ru(II) and the electronic nature of the bound metal centers.

AB - By controlling the extent of oxidation of the polymeric forms of the new class of isolable, polymerizable terthienyl Ru(II) complexes 1, one can modulate both the binding strength of the polymer backbone for Ru(II) and the electronic nature of the bound metal centers.

KW - Conducting materials

KW - P ligands

KW - Polymers

KW - Redox chemistry

KW - Ruthenium

UR - http://www.scopus.com/inward/record.url?scp=0033520392&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033520392&partnerID=8YFLogxK

U2 - 10.1002/(SICI)1521-3773(19990903)38:17<2565::AID-ANIE2565>3.0.CO;2-U

DO - 10.1002/(SICI)1521-3773(19990903)38:17<2565::AID-ANIE2565>3.0.CO;2-U

M3 - Article

AN - SCOPUS:0033520392

SN - 1433-7851

VL - 38

SP - 2565

EP - 2568

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 17

ER -

Weinberger DA, Higgins TB, Mirkin CA, Liable-Sands LM, Rheingold AL. Terthienyl-based redox-switchable hemilabile ligands: Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments? Angewandte Chemie - International Edition. 1999 Sep 3;38(17):2565-2568. doi: 10.1002/(SICI)1521-3773(19990903)38:17<2565::AID-ANIE2565>3.0.CO;2-U

Terthienyl-based redox-switchable hemilabile ligands: Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments?

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

CCDC 108910: Experimental Crystal Structure Determination

Cite this

Terthienyl-based redox-switchable hemilabile ligands: Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments?

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 108910: Experimental Crystal Structure Determination

Cite this