Terthienyl-based redox-switchable hemilabile ligands: Transition metal polymeric complexes with electrochemically tunable or switchable coordination environments?

Dana A. Weinberger, Thomas B. Higgins, Chad A. Mirkin*, Louise M. Liable-Sands, Arnold L. Rheingold

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

38 Scopus citations

Abstract

By controlling the extent of oxidation of the polymeric forms of the new class of isolable, polymerizable terthienyl Ru(II) complexes 1, one can modulate both the binding strength of the polymer backbone for Ru(II) and the electronic nature of the bound metal centers.

Original languageEnglish (US)
Pages (from-to)2565-2568
Number of pages4
JournalAngewandte Chemie - International Edition
Volume38
Issue number17
DOIs
StatePublished - Sep 3 1999

Keywords

  • Conducting materials
  • P ligands
  • Polymers
  • Redox chemistry
  • Ruthenium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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