Te6,[Te8Cl18]2-,andTeCl 3-: New tellurium and chlorotellurato ligands in the Re6 solid-state cluster compounds Re6Te16Cl18 and Re6Te16Cl6

Yuri V. Mironov; Michael A. Pell; James A. Ibers

Te₆,[Te₈Cl₁₈]^2-,andTeCl ₃^-: New tellurium and chlorotellurato ligands in the Re₆ solid-state cluster compounds Re₆Te₁₆Cl₁₈ and Re₆Te₁₆Cl₆

Yuri V. Mironov, Michael A. Pell, James A. Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Re₆ octahedra inside Te₈ cubes is a common feature of both title compounds. The picture on the right shows a section of the structure of Re₆Te₁₆Cl₁₈, in which the Re₆ octahedron and the binding of the cluster to the [Te₈Cl₁₈]² ligand are apparent. Different binding to ligands results in a three-dimensional structure for Re₆Te₁₆,Cl₁₈, and a two- dimensional structure for Rc₆Te₁₆Cl₆.

Original language	English (US)
Pages (from-to)	2854-2856
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	35
Issue number	23-24
State	Published - 1997

Keywords

Clusters
Rhenium compounds
Structure elucidation
Tellurium compounds

ASJC Scopus subject areas

General Chemistry
Catalysis

Cite this

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title = "Te6,[Te8Cl18]2-,andTeCl 3-: New tellurium and chlorotellurato ligands in the Re6 solid-state cluster compounds Re6Te16Cl18 and Re6Te16Cl6",

abstract = "Re6 octahedra inside Te8 cubes is a common feature of both title compounds. The picture on the right shows a section of the structure of Re6Te16Cl18, in which the Re6 octahedron and the binding of the cluster to the [Te8Cl18]2 ligand are apparent. Different binding to ligands results in a three-dimensional structure for Re6Te16,Cl18, and a two- dimensional structure for Rc6Te16Cl6.",

keywords = "Clusters, Rhenium compounds, Structure elucidation, Tellurium compounds",

author = "Mironov, \{Yuri V.\} and Pell, \{Michael A.\} and Ibers, \{James A.\}",

year = "1997",

language = "English (US)",

volume = "35",

pages = "2854--2856",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "23-24",

}

TY - JOUR

T1 - Te6,[Te8Cl18]2-,andTeCl 3-

T2 - New tellurium and chlorotellurato ligands in the Re6 solid-state cluster compounds Re6Te16Cl18 and Re6Te16Cl6

AU - Mironov, Yuri V.

AU - Pell, Michael A.

AU - Ibers, James A.

PY - 1997

Y1 - 1997

N2 - Re6 octahedra inside Te8 cubes is a common feature of both title compounds. The picture on the right shows a section of the structure of Re6Te16Cl18, in which the Re6 octahedron and the binding of the cluster to the [Te8Cl18]2 ligand are apparent. Different binding to ligands results in a three-dimensional structure for Re6Te16,Cl18, and a two- dimensional structure for Rc6Te16Cl6.

AB - Re6 octahedra inside Te8 cubes is a common feature of both title compounds. The picture on the right shows a section of the structure of Re6Te16Cl18, in which the Re6 octahedron and the binding of the cluster to the [Te8Cl18]2 ligand are apparent. Different binding to ligands results in a three-dimensional structure for Re6Te16,Cl18, and a two- dimensional structure for Rc6Te16Cl6.

KW - Clusters

KW - Rhenium compounds

KW - Structure elucidation

KW - Tellurium compounds

UR - https://www.scopus.com/pages/publications/0030484142

UR - https://www.scopus.com/inward/citedby.url?scp=0030484142&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0030484142

SN - 1433-7851

VL - 35

SP - 2854

EP - 2856

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 23-24

ER -

Te₆,[Te₈Cl₁₈]^2-,andTeCl ₃^-: New tellurium and chlorotellurato ligands in the Re₆ solid-state cluster compounds Re₆Te₁₆Cl₁₈ and Re₆Te₁₆Cl₆

Abstract

Keywords

ASJC Scopus subject areas

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