Tetrahedral zinc blende tin sulfide nano-and microcrystals

Eric C. Greyson; Jeremy E. Barton; Teri W. Odom

doi:10.1002/smll.200500460

Tetrahedral zinc blende tin sulfide nano-and microcrystals

Eric C. Greyson^*, Jeremy E. Barton, Teri W. Odom

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

156 Scopus citations

Abstract

The growth of 3D tetrahedral crystals of tin sulfide (SnS) with the zinc blend (ZB) structure was investigated. A morphological yield greater than 90% was achieved and 2D plates of SnS with an orthorhombic structure was produced by increasing the reaction temperature. Scanning electron micrographs (SEM) images revealed that the SnS particles were tetrahedral in shape. It was observed that the optical behavior of the tetrahedral particles emphasized the importance of the crystal structure on the properties of SnS. The formation of nanoparticles with crystal structures different from their bulk is important because it provides another strategy to obtain unique optical properties without confinement effects.

Original language	English (US)
Pages (from-to)	368-371
Number of pages	4
Journal	Small
Volume	2
Issue number	3
DOIs	https://doi.org/10.1002/smll.200500460
State	Published - Mar 2006

Keywords

Chalcogenides
Inorganic chemistry
Nanocrystals
Synthesis design
Tin

ASJC Scopus subject areas

Biotechnology
Biomaterials
Chemistry(all)
Materials Science(all)

Access to Document

10.1002/smll.200500460

Cite this

@article{a52efb505369427a8b1ffcc1e33aa4ec,

title = "Tetrahedral zinc blende tin sulfide nano-and microcrystals",

abstract = "The growth of 3D tetrahedral crystals of tin sulfide (SnS) with the zinc blend (ZB) structure was investigated. A morphological yield greater than 90% was achieved and 2D plates of SnS with an orthorhombic structure was produced by increasing the reaction temperature. Scanning electron micrographs (SEM) images revealed that the SnS particles were tetrahedral in shape. It was observed that the optical behavior of the tetrahedral particles emphasized the importance of the crystal structure on the properties of SnS. The formation of nanoparticles with crystal structures different from their bulk is important because it provides another strategy to obtain unique optical properties without confinement effects.",

keywords = "Chalcogenides, Inorganic chemistry, Nanocrystals, Synthesis design, Tin",

author = "Greyson, {Eric C.} and Barton, {Jeremy E.} and Odom, {Teri W.}",

year = "2006",

month = mar,

doi = "10.1002/smll.200500460",

language = "English (US)",

volume = "2",

pages = "368--371",

journal = "Small",

issn = "1613-6810",

publisher = "Wiley-VCH Verlag",

number = "3",

}

TY - JOUR

T1 - Tetrahedral zinc blende tin sulfide nano-and microcrystals

AU - Greyson, Eric C.

AU - Barton, Jeremy E.

AU - Odom, Teri W.

PY - 2006/3

Y1 - 2006/3

N2 - The growth of 3D tetrahedral crystals of tin sulfide (SnS) with the zinc blend (ZB) structure was investigated. A morphological yield greater than 90% was achieved and 2D plates of SnS with an orthorhombic structure was produced by increasing the reaction temperature. Scanning electron micrographs (SEM) images revealed that the SnS particles were tetrahedral in shape. It was observed that the optical behavior of the tetrahedral particles emphasized the importance of the crystal structure on the properties of SnS. The formation of nanoparticles with crystal structures different from their bulk is important because it provides another strategy to obtain unique optical properties without confinement effects.

AB - The growth of 3D tetrahedral crystals of tin sulfide (SnS) with the zinc blend (ZB) structure was investigated. A morphological yield greater than 90% was achieved and 2D plates of SnS with an orthorhombic structure was produced by increasing the reaction temperature. Scanning electron micrographs (SEM) images revealed that the SnS particles were tetrahedral in shape. It was observed that the optical behavior of the tetrahedral particles emphasized the importance of the crystal structure on the properties of SnS. The formation of nanoparticles with crystal structures different from their bulk is important because it provides another strategy to obtain unique optical properties without confinement effects.

KW - Chalcogenides

KW - Inorganic chemistry

KW - Nanocrystals

KW - Synthesis design

KW - Tin

UR - http://www.scopus.com/inward/record.url?scp=32344452013&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=32344452013&partnerID=8YFLogxK

U2 - 10.1002/smll.200500460

DO - 10.1002/smll.200500460

M3 - Article

C2 - 17193052

AN - SCOPUS:32344452013

VL - 2

SP - 368

EP - 371

JO - Small

JF - Small

SN - 1613-6810

IS - 3

ER -

Tetrahedral zinc blende tin sulfide nano-and microcrystals

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this