Tetrapotassium barium bis[tetrathiovanadate(V)], K4Ba[VS 4]2

Fu Qiang Huang; Jiyong Yao; James A. Ibers

doi:10.1107/S160053680604133X

Tetrapotassium barium bis[tetrathiovanadate(V)], K₄Ba[VS ₄]₂

Fu Qiang Huang, Jiyong Yao, James A. Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article

1 Scopus citations

Abstract

The title compound, K₄Ba[VS₄]₂, has been synthesized by the reaction of V and S in a K₂S/BaS flux at 723 K. Its crystal structure is of the K₄Eu[PS₄]₂ structure type and comprises isolated tetrahedral [VS₄]^3- anions separated by K⁺ and Ba²⁺ cations. The site symmetries of the atoms Ba, K1, K2, V, S1, S2, and S3 are 222, .2., ..m, ..m, ..m, 1, and ..m, respectively.

Original language	English (US)
Pages (from-to)	i224-i225
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	11
DOIs	https://doi.org/10.1107/S160053680604133X
State	Published - Nov 1 2006

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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Huang, F. Q., Yao, J., & Ibers, J. A. (2006). Tetrapotassium barium bis[tetrathiovanadate(V)], K₄Ba[VS ₄]₂. Acta Crystallographica Section E: Structure Reports Online, 62(11), i224-i225. https://doi.org/10.1107/S160053680604133X

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abstract = "The title compound, K4Ba[VS4]2, has been synthesized by the reaction of V and S in a K2S/BaS flux at 723 K. Its crystal structure is of the K4Eu[PS4]2 structure type and comprises isolated tetrahedral [VS4]3- anions separated by K+ and Ba2+ cations. The site symmetries of the atoms Ba, K1, K2, V, S1, S2, and S3 are 222, .2., ..m, ..m, ..m, 1, and ..m, respectively.",

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AU - Huang, Fu Qiang

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AU - Ibers, James A.

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AB - The title compound, K4Ba[VS4]2, has been synthesized by the reaction of V and S in a K2S/BaS flux at 723 K. Its crystal structure is of the K4Eu[PS4]2 structure type and comprises isolated tetrahedral [VS4]3- anions separated by K+ and Ba2+ cations. The site symmetries of the atoms Ba, K1, K2, V, S1, S2, and S3 are 222, .2., ..m, ..m, ..m, 1, and ..m, respectively.

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