Tetrapotassium barium bis[tetrathiovanadate(V)], K4Ba[VS 4]2

Fu Qiang Huang; Jiyong Yao; James A. Ibers

doi:10.1107/S160053680604133X

Tetrapotassium barium bis[tetrathiovanadate(V)], K₄Ba[VS ₄]₂

Fu Qiang Huang, Jiyong Yao, James A. Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The title compound, K₄Ba[VS₄]₂, has been synthesized by the reaction of V and S in a K₂S/BaS flux at 723 K. Its crystal structure is of the K₄Eu[PS₄]₂ structure type and comprises isolated tetrahedral [VS₄]^3- anions separated by K⁺ and Ba²⁺ cations. The site symmetries of the atoms Ba, K1, K2, V, S1, S2, and S3 are 222, .2., ..m, ..m, ..m, 1, and ..m, respectively.

Original language	English (US)
Pages (from-to)	i224-i225
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	11
DOIs	https://doi.org/10.1107/S160053680604133X
State	Published - Nov 1 2006

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Tetrapotassium barium bis[tetrathiovanadate(V)], K4Ba[VS 4]2",

abstract = "The title compound, K4Ba[VS4]2, has been synthesized by the reaction of V and S in a K2S/BaS flux at 723 K. Its crystal structure is of the K4Eu[PS4]2 structure type and comprises isolated tetrahedral [VS4]3- anions separated by K+ and Ba2+ cations. The site symmetries of the atoms Ba, K1, K2, V, S1, S2, and S3 are 222, .2., ..m, ..m, ..m, 1, and ..m, respectively.",

author = "Huang, {Fu Qiang} and Jiyong Yao and Ibers, {James A.}",

year = "2006",

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T1 - Tetrapotassium barium bis[tetrathiovanadate(V)], K4Ba[VS 4]2

AU - Huang, Fu Qiang

AU - Yao, Jiyong

AU - Ibers, James A.

PY - 2006/11/1

Y1 - 2006/11/1

N2 - The title compound, K4Ba[VS4]2, has been synthesized by the reaction of V and S in a K2S/BaS flux at 723 K. Its crystal structure is of the K4Eu[PS4]2 structure type and comprises isolated tetrahedral [VS4]3- anions separated by K+ and Ba2+ cations. The site symmetries of the atoms Ba, K1, K2, V, S1, S2, and S3 are 222, .2., ..m, ..m, ..m, 1, and ..m, respectively.

AB - The title compound, K4Ba[VS4]2, has been synthesized by the reaction of V and S in a K2S/BaS flux at 723 K. Its crystal structure is of the K4Eu[PS4]2 structure type and comprises isolated tetrahedral [VS4]3- anions separated by K+ and Ba2+ cations. The site symmetries of the atoms Ba, K1, K2, V, S1, S2, and S3 are 222, .2., ..m, ..m, ..m, 1, and ..m, respectively.

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DO - 10.1107/S160053680604133X

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SP - i224-i225

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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