Tetrapotassium barium bis[tetrathiovanadate(V)], K4Ba[VS 4]2

Fu Qiang Huang, Jiyong Yao, James A. Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticle

1 Scopus citations

Abstract

The title compound, K4Ba[VS4]2, has been synthesized by the reaction of V and S in a K2S/BaS flux at 723 K. Its crystal structure is of the K4Eu[PS4]2 structure type and comprises isolated tetrahedral [VS4]3- anions separated by K+ and Ba2+ cations. The site symmetries of the atoms Ba, K1, K2, V, S1, S2, and S3 are 222, .2., ..m, ..m, ..m, 1, and ..m, respectively.

Original languageEnglish (US)
Pages (from-to)i224-i225
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number11
DOIs
StatePublished - Nov 1 2006

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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