The [(μ3‐WSe4)3(μ3‐Se)2 (Cu3)2]4− Anion, an Inorganic Cluster with a Pin wheel Shape

Christopher C. Christuk; Mohammad A. Ansari; James A. Ibers

doi:10.1002/anie.199214771

The [(μ₃‐WSe₄)₃(μ₃‐Se)₂ (Cu₃)₂]⁴⁻ Anion, an Inorganic Cluster with a Pin wheel Shape

Christopher C. Christuk, Mohammad A. Ansari, James A. Ibers^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A structure incorporating two eclipsed Cu₃ triangles, three bridging μ₃‐WSe 42− units, and two capping μ₃‐Se atoms is formed from a cubane‐like CuSeW cluster on treatment with Li₂Se. This product pictured here (one Se atom is omitted at each W atom) exemplifies one of the structural possibilities for the little‐studied selenidometalates. (Figure Presented.)

Original language	English (US)
Pages (from-to)	1477-1478
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	31
Issue number	11
DOIs	https://doi.org/10.1002/anie.199214771
State	Published - Nov 1992
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry

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title = "The [(μ3‐WSe4)3(μ3‐Se)2 (Cu3)2]4− Anion, an Inorganic Cluster with a Pin wheel Shape",

abstract = "A structure incorporating two eclipsed Cu3 triangles, three bridging μ3‐WSe 42− units, and two capping μ3‐Se atoms is formed from a cubane‐like CuSeW cluster on treatment with Li2Se. This product pictured here (one Se atom is omitted at each W atom) exemplifies one of the structural possibilities for the little‐studied selenidometalates. (Figure Presented.)",

author = "Christuk, {Christopher C.} and Ansari, {Mohammad A.} and Ibers, {James A.}",

year = "1992",

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AU - Ansari, Mohammad A.

AU - Ibers, James A.

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N2 - A structure incorporating two eclipsed Cu3 triangles, three bridging μ3‐WSe 42− units, and two capping μ3‐Se atoms is formed from a cubane‐like CuSeW cluster on treatment with Li2Se. This product pictured here (one Se atom is omitted at each W atom) exemplifies one of the structural possibilities for the little‐studied selenidometalates. (Figure Presented.)

AB - A structure incorporating two eclipsed Cu3 triangles, three bridging μ3‐WSe 42− units, and two capping μ3‐Se atoms is formed from a cubane‐like CuSeW cluster on treatment with Li2Se. This product pictured here (one Se atom is omitted at each W atom) exemplifies one of the structural possibilities for the little‐studied selenidometalates. (Figure Presented.)

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The [(μ₃‐WSe₄)₃(μ₃‐Se)₂ (Cu₃)₂]⁴⁻ Anion, an Inorganic Cluster with a Pin wheel Shape

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