The [Ag{Se2C2(CN)2}(Se6)]3-, [Sb{Se2C2-(CN)2}2]3-, and [As(Se)3(CH2CN)]2-anions: Facile formation of the maleonitrile-diselenolate (mns) ligand, [Se2C2(CN)2]2-

Donna M. Smith; Thomas E. Albrecht-Schmitt; James A. Ibers

doi:10.1002/(SICI)1521-3773(19980504)37:8<1089::AID-ANIE1089>3.0.CO;2-D

The [Ag{Se₂C₂(CN)₂}(Se₆)]^3-, [Sb{Se₂C₂-(CN)₂}₂]^3-, and [As(Se)₃(CH₂CN)]^2-anions: Facile formation of the maleonitrile-diselenolate (mns) ligand, [Se₂C₂(CN)₂]^2-

Donna M. Smith, Thomas E. Albrecht-Schmitt, James A. Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

An unusual route to the maleonitrilediselenolate (mns) ligand has been discovered with the isolation of compounds that contain this ligand bound to silver (structure shown on the right) or antimony. The formation of the [As(Se)₃(CH₂CN)]^2-anion along with possible pathways to the mns ligands is discussed.

Original language	English (US)
Pages (from-to)	1089-1091
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	37
Issue number	8
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19980504)37:8<1089::AID-ANIE1089>3.0.CO;2-D
State	Published - May 4 1998

Keywords

Antimony
Arsenic
Polyanions
Selenium
Silver

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/(SICI)1521-3773(19980504)37:8<1089::AID-ANIE1089>3.0.CO;2-D

Cite this

@article{21f909116a954c1d8fe66f536c8fc0b6,

title = "The [Ag{Se2C2(CN)2}(Se6)]3-, [Sb{Se2C2-(CN)2}2]3-, and [As(Se)3(CH2CN)]2-anions: Facile formation of the maleonitrile-diselenolate (mns) ligand, [Se2C2(CN)2]2-",

abstract = "An unusual route to the maleonitrilediselenolate (mns) ligand has been discovered with the isolation of compounds that contain this ligand bound to silver (structure shown on the right) or antimony. The formation of the [As(Se)3(CH2CN)]2-anion along with possible pathways to the mns ligands is discussed.",

keywords = "Antimony, Arsenic, Polyanions, Selenium, Silver",

author = "Smith, {Donna M.} and Albrecht-Schmitt, {Thomas E.} and Ibers, {James A.}",

year = "1998",

month = may,

day = "4",

doi = "10.1002/(SICI)1521-3773(19980504)37:8<1089::AID-ANIE1089>3.0.CO;2-D",

language = "English (US)",

volume = "37",

pages = "1089--1091",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "8",

}

Smith, DM, Albrecht-Schmitt, TE & Ibers, JA 1998, 'The [Ag{Se₂C₂(CN)₂}(Se₆)]^3-, [Sb{Se₂C₂-(CN)₂}₂]^3-, and [As(Se)₃(CH₂CN)]^2-anions: Facile formation of the maleonitrile-diselenolate (mns) ligand, [Se₂C₂(CN)₂]^2-', Angewandte Chemie - International Edition, vol. 37, no. 8, pp. 1089-1091. https://doi.org/10.1002/(SICI)1521-3773(19980504)37:8<1089::AID-ANIE1089>3.0.CO;2-D

The [Ag{Se₂C₂(CN)₂}(Se₆)]^3-, [Sb{Se₂C₂-(CN)₂}₂]^3-, and [As(Se)₃(CH₂CN)]^2-anions : Facile formation of the maleonitrile-diselenolate (mns) ligand, [Se₂C₂(CN)₂]^2-. / Smith, Donna M.; Albrecht-Schmitt, Thomas E.; Ibers, James A.

In: Angewandte Chemie - International Edition, Vol. 37, No. 8, 04.05.1998, p. 1089-1091.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The [Ag{Se2C2(CN)2}(Se6)]3-, [Sb{Se2C2-(CN)2}2]3-, and [As(Se)3(CH2CN)]2-anions

T2 - Facile formation of the maleonitrile-diselenolate (mns) ligand, [Se2C2(CN)2]2-

AU - Smith, Donna M.

AU - Albrecht-Schmitt, Thomas E.

AU - Ibers, James A.

PY - 1998/5/4

Y1 - 1998/5/4

N2 - An unusual route to the maleonitrilediselenolate (mns) ligand has been discovered with the isolation of compounds that contain this ligand bound to silver (structure shown on the right) or antimony. The formation of the [As(Se)3(CH2CN)]2-anion along with possible pathways to the mns ligands is discussed.

AB - An unusual route to the maleonitrilediselenolate (mns) ligand has been discovered with the isolation of compounds that contain this ligand bound to silver (structure shown on the right) or antimony. The formation of the [As(Se)3(CH2CN)]2-anion along with possible pathways to the mns ligands is discussed.

KW - Antimony

KW - Arsenic

KW - Polyanions

KW - Selenium

KW - Silver

UR - http://www.scopus.com/inward/record.url?scp=0032482114&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032482114&partnerID=8YFLogxK

U2 - 10.1002/(SICI)1521-3773(19980504)37:8<1089::AID-ANIE1089>3.0.CO;2-D

DO - 10.1002/(SICI)1521-3773(19980504)37:8<1089::AID-ANIE1089>3.0.CO;2-D

M3 - Article

AN - SCOPUS:0032482114

SN - 1433-7851

VL - 37

SP - 1089

EP - 1091

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 8

ER -

The [Ag{Se₂C₂(CN)₂}(Se₆)]^3-, [Sb{Se₂C₂-(CN)₂}₂]^3-, and [As(Se)₃(CH₂CN)]^2-anions: Facile formation of the maleonitrile-diselenolate (mns) ligand, [Se₂C₂(CN)₂]^2-

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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CCDC 122908: Experimental Crystal Structure Determination

CCDC 122909: Experimental Crystal Structure Determination

CCDC 100674: Experimental Crystal Structure Determination

Cite this

The [Ag{Se2C2(CN)2}(Se6)]3-, [Sb{Se2C2-(CN)2}2]3-, and [As(Se)3(CH2CN)]2-anions: Facile formation of the maleonitrile-diselenolate (mns) ligand, [Se2C2(CN)2]2-

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 122908: Experimental Crystal Structure Determination

CCDC 122909: Experimental Crystal Structure Determination

CCDC 100674: Experimental Crystal Structure Determination

Cite this

The [Ag{Se₂C₂(CN)₂}(Se₆)]^3-, [Sb{Se₂C₂-(CN)₂}₂]^3-, and [As(Se)₃(CH₂CN)]^2-anions: Facile formation of the maleonitrile-diselenolate (mns) ligand, [Se₂C₂(CN)₂]^2-