The binding of cyclobutane-1 1-dicarboxylatodiammineplatinum(II) by α-cyclodextrin in aqueous solution

David R. Alston, Terence H. Lilley, J. Fraser Stoddart

Research output: Contribution to journalArticlepeer-review

49 Scopus citations

Abstract

Microcalorimetry and1H n.m.r. spectroscopy have established that Pt(NH3)2(CBDCA()C BDCA = cyclobutane- 1,l-dicarboxylato) and α -cyclodextrin (α -CD) form a 1: 1 adduct in water with a standard free energy change (-∆G°) in the region of 10.4-13.0 kJ mol-1 at 22-25 °C.

Original languageEnglish (US)
Pages (from-to)1600-1602
Number of pages3
JournalJournal of the Chemical Society - Series Chemical Communications
Issue number22
DOIs
StatePublished - 1985

ASJC Scopus subject areas

  • Molecular Medicine

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