TY - JOUR
T1 - The binding of neutral platinum complexes by crown ethers. X-ray crystal structures of [trans-PtCl2(PMe3)NH3.dibenzo-18- crown-6] and [{trans-PtCl2(PMe3)NH3} 2.18-crown-6]
AU - Colquhoun, Howard M.
AU - Stoddart, J. Fraser
AU - Williams, David J.
PY - 1981
Y1 - 1981
N2 - Complexes of the type trans-PtCl2(L)NH3 where L = PMe3 (1), PEt3 (2), and NH3 (3) co-ordinate to 18-crown-6 (18C6) and dibenzo-18-crown-6 (DB18C6) by hydrogen bonding of their NH3 ligands, forming the crystalline adducts [(1)-DB18C6], [(2)-DB18C6], [(1)2-18C6], [(2)2-18C6], and [(3)-18C6]n which also display considerable stability in solution.
AB - Complexes of the type trans-PtCl2(L)NH3 where L = PMe3 (1), PEt3 (2), and NH3 (3) co-ordinate to 18-crown-6 (18C6) and dibenzo-18-crown-6 (DB18C6) by hydrogen bonding of their NH3 ligands, forming the crystalline adducts [(1)-DB18C6], [(2)-DB18C6], [(1)2-18C6], [(2)2-18C6], and [(3)-18C6]n which also display considerable stability in solution.
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U2 - 10.1039/C39810000847
DO - 10.1039/C39810000847
M3 - Article
AN - SCOPUS:37049096551
SN - 1359-7345
SP - 847
EP - 849
JO - Journal of the Chemical Society D: Chemical Communications
JF - Journal of the Chemical Society D: Chemical Communications
IS - 16
ER -