TY - JOUR
T1 - The chameleonic nature of diazaperopyrenium recognition processes
AU - Basuray, Ashish N.
AU - Jacquotderouville, Henri Pierre
AU - Hartlieb, Karel J.
AU - Kikuchi, Takashi
AU - Strutt, Nathan L.
AU - Bruns, Carson J.
AU - Ambrogio, Michael W.
AU - Avestro, Alyssa Jennifer
AU - Schneebeli, Severin T.
AU - Fahrenbach, Albert C.
AU - Stoddart, J. Fraser
PY - 2012/11/19
Y1 - 2012/11/19
N2 - Two for the price of one! The diazaperopyrenium dication behaves dichotomously in a homo- and heterophilic manner, allowing for complexation with itself and a variety of π-electron-rich donors. This chameleonic characteristic, in addition to its electronic properties, leads to self-assembled nanowires in the solid state, as well as to its acting as a template for aromatic crown ethers to form a [3]- and two [2]rotaxanes (see picture).
AB - Two for the price of one! The diazaperopyrenium dication behaves dichotomously in a homo- and heterophilic manner, allowing for complexation with itself and a variety of π-electron-rich donors. This chameleonic characteristic, in addition to its electronic properties, leads to self-assembled nanowires in the solid state, as well as to its acting as a template for aromatic crown ethers to form a [3]- and two [2]rotaxanes (see picture).
KW - noncovalent interactions
KW - perylene
KW - rotaxanes
KW - self-assembly
KW - supramolecular chemistry
UR - http://www.scopus.com/inward/record.url?scp=84869391837&partnerID=8YFLogxK
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U2 - 10.1002/anie.201205089
DO - 10.1002/anie.201205089
M3 - Article
C2 - 23023995
AN - SCOPUS:84869391837
VL - 51
SP - 11872
EP - 11877
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 47
ER -